离子液体催化酯化反应的研究-生物化工专业论文.docxVIP

AbstractAbstract Abstract Abstract Tl矾e kinds of novel environmental．friendly plasticizers have been successfully synthesized by esterification using a series of acidic ionic liquids as catalysts．The catalytic activity of different ionic liquids have been examined and compared．Then we have selected several kinds of ionic liquids which are of excellent catalytic activities and Can be reused after the esterification．We have also studied the optimum reaction conditions of synthesizing the novel plasticizers，including the reuse performances of the ionic liquids． Ten kinds of ionic liquids were synthesized and their structures were examined by IR and NMR．And the Bronsted acidic and acidity of the ionic liquids have been researched through IR,the thermal stabilities of the ionic liquids have been examined by TG The results showed that the ionic liquids are of strong acidic and good thermal abilities． For the synthesis of 1．2-cyclohexane dicarboxylates and TBC，three kinds of HS03-functionalized ionic liquids，【HS03-pN(C2Hs)3]HS04，【HS03-pmim]HS04 and [HS03-pmim]PTSA，showed beaer catalytic activity compared to the other acidic ionic liquids．They also showed good reuse performances since they could be easily separated from the products after reaction．The reaction conditions of using these Bronsted acidic and HS03一functionalized ionic liquids were determined by single factor experiments． 111e optimum reaction conditions of synthesizing dibutyl 1,2-cyclohexane dicarboxylates(DBCH)using ionic liquids as catalysts was studied．And the results were determined as follows：molar ratio of butanol to hexahydrophthalic anhydride(HHPA)Was 2．5：1，amount of catalyst WaS 1％(based on the mass of HHPA)，reaction temperature Was 130．150 oC，reaction time was 8 h． nle condition of synthesizing dioctyl 1,2一cyclohexane dicarboxylate(DIOCHl using ionic liquids as catalysts Was studied．The optimum reaction conditions of esterification were determined as follows：molar ratio of isooctanol to HHPA Was