锂离子动力电池正极材料Li2FeSiO4的制备和电化学性能的研究-机械设计及理论专业论文.docxVIP

西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 万方数据 万方数据 Research on Synthesis and Electrochemical Performance of Li2FeSiO4/Cathode Material for Lithium-ion Power Batteries Speciality: Mechanical Design and Theory Name : Qiang Jing Instructor: Prof. Xu Yunhua ABSTRACT Lithium-ion batteries is the first choice of power supply due to its high theoretical capacity 、 high specific energy 、 no environmental pollution and no memory effect. Cathode material as one of the key materials of lithium-ion batteries, The limitation of its performance has become a bottleneck for the performance of lithium batteries, the requisites for the cathode material of power battery are low cast and long cycle life, besides the good safety performance is the most important. Li2FeSiO4 as a new type of silicate type anion material, its advantages contain high theoretical capacity, cheap and environmentally friendly source of raw materials, good thermal stability. Compared with layered (LiCoO2) and spinel (LiMn2O4) cathode materials, Li2FeSiO4 is more safe because of its stable structure , which make Li2FeSiO4 become a new promising kind of cathode materials in the field of power lithium ion battery. But the electronic conductivity and ion diffusion velocity is low, which hinder the large current discharge ability of Li2FeSiO4. Based on the above disadvantages of Li2FeSiO4, this paper adopts the ion doping and carbon coating method to enhance the conductivity properties of Li2FeSiO4 material. The microstructure, grain size and electrochemical performance of material were analyzed by the method of vanadium ion with different valence doped on Fe sites and Si sites and the citric acid acts as carbon source for material. The specific work is as follows: Doped by vanadium at Fe sites influence on Li2FeSiO4 In this paper, Li2Fe(1-x)VxSiO4 lithium-ion cathode materials with V3+ doped at Fe sites was synthesized by machinery-solid-state method. The structure and morphology of the Li2FeSiO4 with V3+ doped at Fe