聚鲁米诺与其复合物的化学氧化合成与性质分析.pdfVIP

Abstract Conductive polymer has been paid much attention. As an aniline derivative, the polymerization of luminol and the study of polyluminol in electrochemistry and electrochemiluminescence (ECL) have also been paid much attention. The new ECL sensing methods using polyluminol as luminescent reagent not only broadened the application of ECL of luminol, but also simplified the process of construction of luminol-based ECL sensor and the analysis procedure, which is favor for the development of instrument miniaturization and simplification. However, few studies have reported for the synthesis of polyluminol or its composite nanomaterials synthesized in solution and its application. This article focuses on the synthesis of polymeric luminol by chemical oxidation in solution and the properties of polymeric luminol. Firstly, the fluorescence and chemiluminescence properties of polymeric luminol synthesized by chemical oxidative reaction in solution were studied, and the effect of the fluorescence excitation wavelength and medium on the fluorescence of polymeric luminol was studied; the chemiluminescence of the polymeric luminol was studied, too. It was found that maximum fluorescence emission wavelength red shifted obviously for the polymeric luminol compared to luminol, and the polymeric luminol still maintained luminol chemiluminescent property. The resulting polymeric luminol was investigated using UV-visible, infrared IR and thermal gravimetric analysis, and the results showed tha