兰炭基活性炭的制备工艺及性能研究-化学工艺专业论文.docxVIP

西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 Study on the Perparation of Process and Properties of Activated Carbon Based on Blue-coke Specialty： Chemical Technology Name： Liu Changbo Instructor：Prof. Lan Xinzhe ABSTRACT Blue-coke was prepared by the low metamorphic coals by the low temperature dry distillation. And powders appear resulting from production, transportation and storage of blue-coke with high fixed carbon content, low ash and low volatile. The process and method for producing activated carbon using blue-coke powder was studied in this paper and the performance of products were characterized. And develop a new road for the comprehensive utilization of blue-coke powder. The study shows that, blue-coke powder after pretreatment three times was mixed with 20% binder then modeled. Activated carbon was prepared by physical activation method under the conditions: carbonization temperature was 450 ℃ , activation temperature was 900℃, activation time was 1.5h, the amount of water vapor was 50mL/h. And the yield of products was 34.15%, the compressive strength was 9.9MPa, the iodine adsorption value was 1157.4mg/g and the specific surface-area was 448.70m2/g. While the physical-chemical activation method were used to prepare activated carbon under the same conditions. The yield of products was 45.62%, the compressive strength was 14.5MPa, the iodine adsorption value was 1145.8 mg/ g and the specific surface-area was 488.75m2/g. X-ray diffraction analysis shows that the graphitization degree, the irregular degree of its microcrystalline structure and the amorphous carbon content of the products prepared by physical activation method are higher than the products prepared by physical-chemical activation method. The data of pore size distribution shows that the average pore size of the products prepared by the two methods is in the middle of the pore size, it belongs to pore developed activated carbon, but the average pore size of the products