利用Heck反应合成有机光导材料——咔唑类衍生物的合成及研究-无机化学专业论文.docxVIP

摘要光导体是一种重要的信息功能材料，可广泛应用于静电复印．全息照相，计算机终端 摘要 光导体是一种重要的信息功能材料，可广泛应用于静电复印．全息照相，计算机终端 仪器的激光打印．轻印刷制版等。自1938年美国人calson发明了利用感光导电现象的复 写方式一电子照相以来，用于光导体的捌料的开发研究工作发展迅速。近年来，有机光导 体(OPC)的实用化研究工作非常活跃。 目前国内外实用的有机光导体一般采用双层结构，即光生载流子发生层(CGL)和光 生载流予输送层(CTL)。此种结构避免了载流子的复合，大大提高了光生载流子的量子效 率。作为空穴载流子产生材料主要有酞青颜料，多偶氮颜料，茈颜料等。空穴载流子传输 材料主要有咔唑类化合物．重氮化合物，吡嗪类化合物，胨化合物，多芳基胺化合物和多 偶氮化合物等。 本学位论文就是在认真分析和总结文献的基础上，利用金属有机化学中的Heck反应 设计合成了一系列咔唑类衍生物，并对其光物理性质进行了测试。合成具有原料易得，方 法简单等优点。结果表明：合成的咔唑类衍生物比原料具有更良好的光学性质，具有一定 的应用前景。 AbstractPhotoconductor Abstract Photoconductor iS important information—function material．which be widely applied in xerography,laser minepgraph of computer’S terminal apparatus，printing lightly and plate making,etc．Since electronic photograph(a duplicating form by using of the phenomenon of sensitize conducting electricity)being invented by Calson，all American，in 1938，the development of the material making of photoconductor is very active．In years，the pragmatic research ofOPC is very revitalizing,which has caught the world’S attentions． As present the pragmatic OPC home and abroad is generally using double-layer ie CGL and CTL．This avoids the composition of carriers，and enhances the quantum efficiency of carriers．The generation materials are mainly phthalocyanine pigments， multiazopigments and perlene compounds ate，and the charge transferring materials are carbazole compounds，oxadiazole compounds，pyrazoline compounds，hydyazone compounds， polyarylated amine compounds and stilbene compounds． On the basis of carefully analyzing and summarizing literature this thesis designs and synthesizes series of derivatives of carbazole by using the typical reaction-Heck reaction． Heck reaction，since its discovery in the early 1970s，the palladium catalyzied arylation ofolefins has been applied diverse array of fields，ranging from natural product synthesis material science biorganic chemistry．It is considered be broadly useful method for the single-step arylation ofolefms． This synthesis has the following ad