锂离子电池负极材料硫化钼的制备及电化学性能研究-材料学专业论文.docxVIP

华中 科技 大学 华 中 科 技 大 学 硕 士 学 位 论 文 II万方数据 II 万方数据 ABSTRACT Lithium ion batteries (LIBs) have been widely used in portable electronic devices for its high energy density, green and durability. They have attracted significant attentions as the most promising power sources for electric vehicles (EVs). As for the anode materials in LIBs, graphite has been widely commercialized due to its natural abundance, flat potential profile versus lithium, high coulombic efficiency and structural stability during cycling. However, it cannot fully meet the energy density requirement in EVs due to its relatively small theoretical specific capacity (372 mAh/g). Therefore, alternative anode materials with higher specific capacity and good cycling performance are desirable for LIBs. Molybdenum disul?de (MoS2), a typical transition metal dichalcogenide with unique sandwich structure, has shown potential applications in the fields of lubrication, catalysis, hydrogen storage, and so on. The layered structure of MoS2 enables easy intercalation of Li+, without obvious increase in volume. In this thesis, we focused on the studies of MoS2 used as anode material for lithium ion batteries. A facile process was developed to synthesize hierarchical MoS2 in the basic solution via a hydrothermal route, the influence of hydrothermal preparation parameters on the material properties and the morphology evolution of MoS2 were systematically investigated. We also explored the relationship between the microstructures and electrochemical performances of MoS2. MoS2 was synthesized by employing ammonium heptamolybdate and thiourea as starting materials and then post-annealing in N2 atmosphere at 450 °C for 5 h. The morphologies of the MoS2 products can be tuned from the porous flowers to the dense spheres by addition of NaOH. Experimental results show that the MoS2 products have good crystallinity. The formation mechanism of the MoS2 is proposed by that the dense MoS2 spheres are evolved from the porous MoS2