邻甲酚绿色催化羟化研究-工业催化专业论文.docxVIP

郑州人学硕士学位论文当反应体系中没有加入偶合反应试剂时，当加入过氧化氢后，反应液很快变棕色， 郑州人学硕士学位论文 当反应体系中没有加入偶合反应试剂时，当加入过氧化氢后，反应液很快变棕色， 最终变成黑色，在最终的产物中，可以发现产生了大量的焦油。当加入一定量的偶 合反应试剂后，溶液始终不变黑，最终产物中也没有焦油产生，达到了清洁催化氧 化的效果。此时，偶合剂二甲亚砜／邻甲酚为8：10(摩尔比1。 关键词：羟基磷酸铜邻甲酚催化羟基化过氧化氢焦油 Il 郑州大学硕士学位论文ABSTRACT 郑州大学硕士学位论文 ABSTRACT Heterogeneous catalytic reaction is all important research topic，has achieved prodigious development．Phenolic compounds is an important industrial law materials， which normally needs indirect synthesis．therefore the production process is mor℃ complicated．In theory,it is feasible to directly hydroxylating to synthesize hydroxybenzene by green oxidants which are air,oxygen and hydrogen peroxide．In recent years，there are a large number ofinvestigations about how to directly hydroxyl ate benzene to prepare Phenol and how to directly hydroxylate phenol to prepare dihydroxybenzene．But the research about direct hydroxylation of other displaced hydroxybenzene was reported a fat lot．Because of the concerted effect of substitutes，the selectivity of reaction which displaces the unfavorable place is extraordinarily low．And the derivates ofproducts hydroxylated by o-cresol，which is methyldihydroxybenzene，ale important intermediate of fine chemical engineering and the additional value are considerable． It is the most potentially industrial process that hydroxyl free radical directly substitutes the hydrogen atom on aromatic ring and the selection of catalyzer Was the key of direct hydroxylation．This dissertation researched the preparation condition of copper hydroxyphosphate(Cu2(OH)P04)and the process for synthesizing methyldihydroxybenz- erie by directly hydroxylating O-cresol with copper hydroxyphosphate prepared by myself． We could carry out cleanly catalytic oxidation with coupled reaction in allusion to the problem of deepness oxidation in the hydroxylation process．As a result,the cost of copper hydroxyphosphate Was low,the process was easy and it had good catalytic activity, It WaS a process that methyldihydroxyb