锂离子超级电容器的研究-高分子化学与物理专业论文.docxVIP

I I 锂离子超级电容器的研究 中文摘要 中文摘要 超级电容器是一种高功率密度的无源储能元件，随着它的问世，如何应用好超级 电容器，是科技工作者的一个热门话题。超级电容器具有充放电速度快、效率高、循 环寿命长、工作温度范围宽、可靠性好等诸多优点，但是与传统的二次电池如锂离子 电池相比，超级电容器的能量密度较低。 本研究主要通过用传统方法做成了以活性碳为电极的对称性电容器，和以石墨、 Li4Ti5O12取代一个活性炭电极的非对称性电容器做了对比，尝试得到能量密度更高、 循环寿命更好的超级电容器。主要研究内容如下： （1）采用活性炭为对称性电极，以 1mol/L LiPF6/EC+DEC(体积比 1:1)为电解液， 用不同的正负电极质量比，获得最佳的电容器 （2）以改进的固相法得到的 Li4Ti5O12 材料为基础，研究了 TiN 表面修饰对其电 化学性能的影响。结果表明：表面修饰 TiN 能够显著提高 Li4Ti5O12 材料的导电性， 倍率性能和循环寿命。 （3）以 Li4Ti5O12 为负极，以石墨为正极，探究出了一种性能更好的体系，得到 了比较理想的超级电容器。 关键词：超级电容器；活性炭；锂离子二次电池； Li4Ti5O12 作者：刘 旭 指导老师：郑军伟 教授 II II Abstract 锂离子超级电容器的研究 The performance research of Lithium-ion supercapacitors Abstract Supercapacitor is a kind of high power density of passive energy storage devices, along with its coming out, how to apply supercapacitor well is a hot topic for the workers. Supercapacitor with charge and discharge speed, high efficiency and long cycling life, wide working temperature range, good reliability, and many other advantages, but with the traditional secondary battery than such as lithium ion battery, supercapacitor energy density is lower. This research mainly by using traditional methods to make it to the symmetry of activated carbon electrode capacitor, and with graphite, Li4Ti5O12 replace an activated carbon electrode asymmetry of the capacitor made the contrast, try to get higher energy density, circle life better super capacitors. The main contents are as follows: The active carbon electrode for symmetry, with 1 mol/L LiPF6 / EC + DEC (volume ratio of 1 to 1) for the electrolyte, with different positive and negative electrode than quality, get the best capacitors To improve solid phase method get Li4Ti5O12 materials as the foundation, study the TiN surface modification on the electrochemical performance influence. The results show that surface modification TiN can obviously improve the conductivity of the Li4Ti5O12 materials, rate of performance and circle life To Li4Ti5O12 for negative with graphite as positive, explore a pe