反相气相色谱法探究cpc_膨润土对vocs的吸附作用新.pdfVIP

第 23 卷第 4 期 环 　境 　科 　学 　学 　报 Vol. 23 ,No. 4 2003 年 7 月 ACTA SCIENTIAE CIRCUMSTANTIAE Jul. ,2003 ( ) 文章编号 2003 　　　中图分类号 :X132 　　　文献标识码 :A 反相气相色谱法研究 CPC膨润土对 VOCs 的 吸附作用 ( ) 田森林 ,朱利中 ,施 　耀　浙江大学环境与资源学院 ,杭州 　310028 摘要 :运用反相气相色谱法研究了20 种 VOCs 在 CPC膨润土上的吸附平衡及吸附热. 结果表明,CPC膨润土对 VOCs 的吸附 有较强选择性 ,吸附能力与有机物的分子量 、分子结构 、饱和蒸气压等物理化学性质有关 ,对苯系物和分子量较大的酯类和 酮类等吸附能力较强. 温度较低时 ,CPC膨润土对VOCs 的吸附能力较强 ,吸附热较大 ;吸附热与VOCs 的沸点蒸发热相当 ,但 比活性炭等常规吸附剂对 VOCs 的吸附热小. 关键词 :有机膨润土 ;吸附;挥发性有机物 ;反相气相色谱 Study on sorption characterization of VOCs onto CPCbentonite by inverse gas chromatography ( TIAN Senlin , ZHU Lizhong , SHI Yao 　 College of Environmental and Resource Sciences , Zhejiang University , Hangzhou 　 310028 , China) Abstract :Sorption properties and enthalpies of 20 VOCs onto CPCorganobentonite were studied by inverse gas chromatography. CPCbentonite showed strong selectivity toward VOCs , and its sorption capacity depended on physicochemical properties of VOCs , such as molecular weight , structure , and saturated vapor pressure. The sorption abilities of BTEX , esters and ketones with greater molecular weights to CPCbentonite were greater than the others. The sorption properties were obviously influenced by temperature. The sorption enthalpies of VOCs onto CPC bentonite were similar fo heating of evaporation , but smaller than that of common adsorbents. Keywords :organobentonite ; sorption ; volatile organic compounds ; inverse gas chromatography 与膨润土原土相比,有机膨润土有机碳含量增加 、疏水性提高 、对有机物吸附能力增强 ,在 有机废水 、废气吸附处理和土壤 、地下水污染修复中有很好的应用前景. 但迄今研究得最多的