生物基聚酰胺研究进展.pdf

生 物 工 程 学 报 黄正强 等/生物基聚酰胺研究进展 761 Chinese Journal of Biotechnology /cjbcn June 25, 2016, 32(6): 761−774 DOI: 10.13345/j.cjb.160016 ©2016 Chin J Biotech, All rights reserved 综 述 黄正强，崔喆，张鹤鸣，付鹏，赵清香，刘民英 450001 喆 , , , . . , 2016, 32(6): 761–774. Huang ZQ, Cui Z, Zhang HM, et al. Progress in bio-based polyamides. Chin J Biotech, 2016, 32(6): 761–774. 摘 要: 生物基聚酰胺是指制备聚酰胺的原料来源于生物质材料，生物基聚酰胺的原料主要有生物基氨基酸、 生物基内酰胺、生物基二元酸、生物基二元胺等。本文论述了不同生物基原料的来源、制备方法以及相应的生 物基聚酰胺的性能；重点论述了生物基聚酰胺PA11 和PA1010 的原料制备方法、合成方法以及改性研究进展； 对生物基聚酰胺的种类、产业化研究现状进行了总结，并对我国生物基聚酰胺的发展提出建议。 关键词: 生物基，可再生原料，聚酰胺，制备工艺，性能 Progress in bio-based polyamides Zhengqiang Huang, Zhe Cui, Heming Zhang, Peng Fu, Qingxiang Zhao, and Minying Liu School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China Abstract: Bio-based polyamides are environment-friendly polymers. The precursors of bio-based polyamides come from bio-based materials such as castor oil, glucose and animal oil. Bio-based polyamides precursors include bio-based amino acids, bio-based lactams, bio-based diprotic acid and bio-based diamines. In this paper, we discussed the route of the precursors of bio-based polyamides that come from bio-based materials. We discussed the properties of bio-based polyamides. Bio-based PA11and bio-based PA1010 are well-known bio-based polyamides; we discussed the origin materials of the precursors, the route of manufacturing bio-based PA11 and PA1010, and their modifications status. The variety, classification and commercial production of bio-based polyamides were described in details,