上海交通沿线农田土壤中PAHs分布特征及源解析-中国环境科学.PDF

中国环境科学 2019,39(2) ：741~749 China Environmental Science 上海交通沿线农田土壤中 PAHs 分布特征及源解析 张 希 1,杨 静 1,刘 敏 1*,陈 星 1,吴 建 2 (1.华东师范大学地理科学学院,教育部地理信息科学重点实验室,上海 200241 ；2.上海市环境科学研究院,上海 200233) 摘要：为探讨交通干线对周围农田土壤环境中 16 种优先多环芳烃(PAHs)累积的影响,采集了上海市交通干线旁与道路垂向分布的 70 个农田土壤表层 样品及 2 个土壤柱样品,系统分析了土壤中 16 种优控 PAHs 的含量、组成及来源.结果表明上海交通干线旁农田表层土壤 PAHs 含量范围为 23.16~21250.25ng/g,平均值为 928.16ng/g,且随着与防护林距离的增加呈现出先下降后增加而后又下降的趋势,农田土壤柱中 PAHs 含量则表现出随着 距土壤深度的增加而上升的趋势.基于正定矩阵因子分析(PMF)模型及特征因子比值法的来源辨析结果,表明表层土壤和土壤柱中的 PAHs 均主要来源 于煤、生物质的燃烧及交通排放. 关键词：交通干线；农田土壤；多环芳烃；分布特征；源解析 中图分类号：X142 文献标识码：A 文章编号：1000-6923(2019)02-0741-09 1 Distribution characteristics and source analysis of PAHs in farmland soils along Shanghai traffic artery. ZHANG Xi , YANG Jing1 1* 1 2 , LIU Min , CHEN Xing , WU Jian (1.Key Laboratory of Geographic Information Science of the Ministry of Education, School of Geographic Sciences, East China Normal University, Shanghai 200241, China；2.Shanghai Acadamy of Environmental Sciences, Shanghai 200233, China). China Environmenal Science, 2019,39(2)：741~749 Abstract ：In order to investigate the influence of traffic emission on the accumulation of 16 polycyclic aromatic hydrocarbons (PAHs) known as priority pollutants in the surrounding farmland soils, seventy soil surface samples and two soil cores samples were collected within 500m of the Shanghai traffic artery. The concentrations, compositions and sources of 16PAHs were systematically analyzed. The results showed that the concentrations of Σ16 PAHs in the surface soils of the farmland along the Shanghai traffic artery was 23.16~21250.25ng/g, with an average of 928.16ng/g. Along th