改性凹凸棒石脱除燃煤PM0.2及重金属的研究.docVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：15xxxx 改性凹凸棒石脱除燃煤PM0.2及重金属的研究 王浩，刘小伟，徐义书, 张煜枫，徐明厚 （华中科技大学煤燃烧国家重点实验室，武汉 437004） (Tel Email:1824594845@) 摘 要 制备盐酸改性凹凸棒石，按照3: 100的添加比例与煤粉混合，在高温沉降炉上进行1500°C条件下的燃烧实验，利用低压撞击器（LPI）收集产生的颗粒物，测试获得不同粒径颗粒物的生成量与重金属含量。结果表明：天然及改性凹凸棒石减排超细颗粒物的效率为28.5%和44.1%；同时，改性提高了吸附剂对于超细颗粒物上重金属Pb和V的减排效果。盐酸改性去除了凹凸棒石中杂质碳酸盐，且H+置换了层间原有金属离子、增加了游离SiO2和Si-OH含量，从而提升了其脱除效果。 关键词 改性凹凸棒石；添加剂；超细颗粒物；重金属；燃煤 Study on the emission characteristics of ultrafine particulate matters and heavy metals during coal combustion by adding attapulgite and modified attapulgite WANG Hao, LIU Xiao-Wei, XU Yi-Shu, ZHANG Yu-Feng, XU Ming-Hou (Huazhong University of Science and Technology, Wuhan 430074, China) Abstract Hydrochloric acid modification was selected to modify attapulgite, which is a kind of typical modification method. Then, pulverized coal was burned with raw and modified attapulgite separately in an electrical heated drop-tube furnace, and the mass size distribution of the fly ash particulate and the mass yield of Pb and V were obtained. The results indicate that, the PM0.2 reduction by adding raw attapulgite and acid modified attapulgite were 28.5% and 44.1%. Compared with raw attapulgite, the modified attapulgite can reduce the mass yield of Pb and V in PM0.2. It is found that the modification by hydrochloric acid can remove carbonate in the attapulgite, H+ replaced the original metal ions between the layers, and the modification also increased the content of free SiO2 and Si-OH. Key words modified attapulgite; additive; ultrafine particulate matters; heavy metals; coal combustion 0 前言 燃煤过程中产生了严重的颗粒物、SOX、NOX以及重金属污染 ADDIN EN.CITE EndNoteCiteAuthorXu/AuthorYear2011/YearRecNum179/RecNumDisplayTextstyle face=superscript[1]/style/DisplayTextrecordrec-number179/rec-numberforeign-keyskey app=EN db-id=wd95pvara2v9xhe0r2nxx22g2tfvdrde5d9v179/keykey app=ENWe