气压烘焙对生物质特性的影响研究.docxVIP

基金项目：国家自然科学基金（5161101059, U1510119），煤转化国家重点实验室基金（J17-18-301） 中国工程热物理学会 燃烧学 学术会议论文 编号：184179 ? 基金项目：国家自然科学基金（ ? 基金项目：国家自然科学基金（51661145010, U1510119），煤转化国家重点实验室基金（J17-18-301） 童珊，肖黎，李显*，汪峰，姚洪 （华中科技大学能源与动力工程学院煤燃烧国家重点实验室，湖北 武汉430074 新疆大学化学化工学院煤炭清洁转化与化工过程自治区重点实验室，新疆，乌鲁木齐，830001） （Tel *Email: xian_li@hust.edu.cn） 摘 要 本文提出了一种生物质气压烘焙方法。 探究了气压烘焙对生物质性质的影响，并对反应机理进行了研究。研究发现，气压烘焙能增强生物质中羰基，羧基和羟基官能团的脱除，获得具有更低挥发分含量，氧含量，更高碳含量和热值的烘焙产物。气压烘焙促进生物质分解的反应机理是气压烘焙过程中产生的挥发性物质与生物质发生二次反应，且压力的存在促进了该二次反应。 关键词 生物质，烘焙，气压 Research about the effect of gas-pressurized torrefaction on biomass characteristics TONG Shan, XIAO Li, LI Xian*, WANG Feng, YAO Hong （State Key Laboratory of Coal Combustion, school of energy and power engineering, Huazhong University of Science and Technology, Hubei 430074, China Key Laboratory of Coal Clean Conversion and Chemical Process Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830000, Xinjiang, China） ABSTRACT: In this work, a gas-pressurized (GP) torrefaction method was proposed to torrefy the biomass. The effect of gas pressure on biomass was studied and the reaction mechanism was investigated in detail. The results indicated that the GP torrefaction enhances the cracking of carbonyl, carboxyl and hydroxyl functional groups in biomass. The GP torrefied biomass had lower volatile matter content, higher carbon content and higher calorific value than the torrefied biomass obtained by conventional method. The the reaction mechanism of gas-pressurized torrefaction was that there were secondary reactions between the volatiles and biomass during the torrefaction. Furthermore, the pressure was also essential for the effective secondary reactions. 0 前言 目前，鉴于能源需求的日益增长以及化石能源的短缺，可再生能源的作用日益突出。 生物质因其储量丰富，硫和氮含量低，可以实现“二氧化碳零排放”等优点，成为非常重要的可再生能源，生物质能年消耗量约占全球能源消耗的10% [1]。目前生物质的利