空气深度分级NOx排放特性CHEMKIN模拟研究.docxVIP

MACROBUTTON MTEditEquationSection2 SEQ MTEqn \r \h SEQ MTSec \r 1 \h SEQ MTChap \r 1 \h 中国工程热物理学会 燃烧学 学术会议论文 编号：184162 空气深度分级NOx排放特性 CHEMKIN模拟研究 王超伟，王长安? 资助项目：国家重点研发计划资助 ? 资助项目：国家重点研发计划资助(2017YFB0602003) (西安交通大学动力工程多相流国家重点实验室，西安，710049） (TelEmail:changanwang@mail.xjtu.edu.cn) 摘 要 本文利用两段PFR反应器构建模型在CHEMKIN中模拟，研究空气深度分级燃烧中各个影响因素，使用生成速率分析和敏感性分析，探求燃料N向NOx的转化路径及原因。模拟结果表明，主燃区α对NOx转化率影响较大，高温强还原氛围能明显降低NOx排放；改变燃烧温度降低NOx排放，应当考虑主燃区，而非燃烬区；当主燃区温度小于1500℃，燃烬风率为35%左右时，NOx排放最低；富燃条件下O2/CO2燃烧增大了OH/H，促进NOx生成；燃烬风位置向后移会降低NOx转化率，改变燃烬风氧浓度NOx转化率几乎不变。本文不仅扩大了前人对空气分级燃烧的研究范围，而且对于前人没有研究的影响因素给出了结果，并且进行了化学反应动力学分析，对实际锅炉运行减少NOx排放具有指导意义。 关键词 空气深度分级；甲烷燃烧；CHEMKIN；NOx CHEMKIN Simulation of NOx Emission of Staged-air Combustion WANG Chaowei, WANG Chang’an, WANG Pengqian，WU Song, CHE Defu (State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China) (Tel: Email: changanwang@mail.xjtu.edu.cn) Abstract: The model used to study fuel-N conversion in air staged combustion including all of factors is established with two PFR in CHEMKIN, and results are analyzed by rate of production and sensitivity analysis. The results show that, stoichiometric ratio of main combustion zone effect NOx emission significantly, especially under high temperature and strong reducing atmosphere conditions. The temperature of main combustion zone should be considered to decrease NOx formation rather than burnout zone. The NOx emission is lowest when the temperature of main combustion zone is lower than 1500℃ and the rate of overfire air is 35%. The staged O2/CO2 combustion under fuel-rich condition increases OH/H ratio leading to more NOx production. The NOx conversion rate will be reduced when the position of overfire air moves backward, and NOx conversion rate will be almost unchanged when the oxygen concentration of ov