基于BaFe2O4与CaO-BaFe2O4引导的甲苯化学链气化制取富氢气体的研究.docxVIP

基于BaFe2O4与CaO-BaFe2O4引导的甲苯化学链气化制取富氢气体的研究 陈静1,2,3,4,，赵坤1,2,3，*，何方1,2,3,5，赵增立1,2,3，黄振1,2,3，魏国强1,2,3，李海滨1,2,3 (1.中国科学院广州能源研究所，广州，510640；2. 中国科学院可再生能源重点实验室，广州，510640；3. 广东省新能源和可再生能源研究开发与应用重点实验室，广州，510640；4. 中国科学技术大学纳米科学技术学院，苏州 215000；5. 桂林理工大学，桂林, 541004) 作者联系电话 Email:cj1668@mail.ustc.edu.cn 摘要：为了研究CaO-BaFe2O4复合载氧体化学链制取富氢气体的机理及过程，本论文将CaO-BaFe2O4和BaFe2O4作为载氧体分别应用于甲苯化学链气化过程中。通过研究反应过程中各气体浓度的变化以及积炭量和甲苯转化率，探究CaO掺杂促进甲苯化学链制氢性能提升的影响。本实验中，采用溶胶凝胶法制备了BaFe2O4并通过固相浸渍法制备CaO-BaFe2O4，再通过XRD,SEM,BET,TPR等物理化学性能表征研究两种载氧体的物理化学性质。固定实验床实验结果表明，添加CaO可促进甲苯转化率，减少CO2的生成，提高H2和总产气量。 关键词：化学链气化；铁酸钡；富氢气体 Preparation of hydrogen rich gas by chemical looping gasification of toluene based on BaFe2O4 and CaO-BaFe2O4 chenjing1,2,3,4,，zhaokun1,2,3，*，hefang1,2,3,5，zhaozengli1,2,3，huangzhen1,2,3，weiguoqiang1,2,3，lihaibin1,2,3 (1.Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China; 2.University of Chinese Academy of Sciences, Beijing 100049, China;3.Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou 510640, China; 4., Nano science and Technology Institute of University of Science and Technology of China, Suzhou 215000; 5 Guilin University of Technology, Guilin, 541004) Contact number:Email:cj1668@mail.ustc.edu.cn Abstract: In order to study the mechanism and process of producing hydrogen rich gas based on CaO-BaFe2O4 in chemical looping gasification process, CaO-BaFe2O4 and BaFe2O4 were prepared as oxygen carriers used in the process of toluene chemical looping gasification. The effect of CaO doping on the performance of toluene chemical looping hydrogen production was investigated by studying the changes of gas concentrations in the reaction process, as well as the amount of carbon deposition and toluene conversion. In this experiment, BaFe2O4 was prepared by sol-gel method and CaO-BaFe2O4 was prepared by solid phase impregnation method, and then the physical and chemical properties