孔隙结构和润湿性对水焦浆稳定性的影响.docVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：15xxxx 孔隙结构和润湿性对水焦浆稳定性的影响 高夫燕，胡长兴*，李建新 (浙江大学宁波理工学院，宁波 315100) (Tel Email:huchx@zju.edu.cn) 摘 要 实验研究了4种石油焦在3种添加剂下成浆的静态稳定性，分析了石油焦微观孔隙结构和表面润湿性对水焦浆稳定性的影响规律。结果表明：石油焦比表面积越小、平均孔径越大，在相同的表观粘度下，浆体越易获得更高的固体浓度和更稳固的三维空间结构，呈现更好的静态稳定性；石油焦颗粒表面润湿性越弱，越易吸附分散剂非极性的疏水基，在颗粒表面形成稳定且显著的吸附层结构，从而有效阻碍颗粒聚结，使浆体表现出较好的稳定性。 关键词 石油焦；水焦浆；稳定性；孔隙结构；表面润湿性 Effects of the microscopic pore structure and the surface wettability of petroleum coke on the stability of petroleum coke water slurry Gao Fuyan, Hu Changxing*, Li Jianxin (Ningbo Institute of Technology，Zhejiang University，Ningbo 315100) Abstract:?The static stability?of slurries, made from four kinds of petroleum coke under three kinds of additives?was studied experimentally, and the effects?of the microscopic pore structure and the surface wettability of petroleum coke on the stability of?petroleum coke water slurry (PCWS) were researched and documented in this paper. The results showed that the PCWS could obtain higher solid concentration and more stable three-dimensional space structure on the same apparent viscosity, showing better stability, as the mean pore diameter increased and the specific surface area decreased. The weaker the surface wettability of petroleum coke particles, the easier it was to adsorb the non-polar hydrophobic base of dispersant. Therefore, it was easy to form stable and significant adsorption layer structure on the weakly wettable surface, which could more effectively block interparticle cohesion and make the slurry present good static stability. Key words：petroleum coke; petroleum coke water slurry (PCWS); stability; pore structure; surface wettability 0 前言 石油焦是石油炼化加工过程剩余的固体残渣[1-3]。近年来，我国石油焦的产量逐年增加，如何从技术和经济两方面使石油焦得到合理利用，已成为企业和社会追求的目标。随着水煤浆技术的发展，由石油焦、水和添加剂制成的水焦浆也受到人们的广泛关注。水焦浆是一种新型清洁高效的液体代油燃料，既可以缓解我国的石油需求压力[4]，又为石油焦的清洁高效利用开辟了新途径[5]。水焦浆的流动特性和油、水煤浆相似，能像油一样输送、