SO42-、Cl-对矿物质冷凝、沾污特性的影响.docVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184503 The project was supported by National Natural Science Foundation of China and National Program of International Science and Technology Cooperation (2015DFA60410). 国家自然科学基金和国家国际科技合作专项(2015DFA60410)资助。 通讯作者：张成，E-mail：chengzhang@；Tel：0278321；Fax：027 第一作者：余圣辉（1993－ ），男，博士163.com。 SO42-、Cl-对矿物质冷凝、沾污特性的影响 余圣辉，张成*，张小培，许豪，方庆艳，陈刚 （华中科技大学 煤燃烧国家重点实验室，湖北 武汉 430074） (Tel Email:yushenghui@) 摘 要 为了研究硫酸盐和氯酸盐对换热器表面钠、钙冷凝、沾污的影响，实验选取五彩湾煤为研究对象，在水平管式炉内模拟900oC烟气的沾污、积灰实验，通过热电偶采集不同区间的温度，XRD、XRF分析样品的成分，SEM、体视显微镜分析样品的形貌特征。结果表明，沾污可以分为钠盐前驱体形成、硅酸盐疏松结构层生长和表面矿物质粘附三个过程，温度对沾污具有选择性，873oC管壁处硅和钙含量高，而591oC管壁处钠含量高，SO42- 在高温时对钠、钙的吸附作用明显，而Cl- 在低温段对钠具有显著吸附作用。 关键词 准东煤；沾污；冷凝特性；换热器；吸附作用 Influence of SO42-and Cl- on Minerals Condensation and Slagging Characteristics Shenghui Yu, Cheng Zhang*, Xiaopei Zhang, Hao Xu, Qingyan Fang and Gang Chen (State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China) ABSTRACT In order to study the effects of sulphate and chlorate on the condensation and accumulation of sodium and calcium on the surface of heat exchangers of coal-fired boilers, Wucaiwan coal (WCW) was selected for the study. Slagging experiment of flue gas at 900oC in heat exchanger was simulated in a horizontal tube furnace. The thermocouples were used to collect the temperature of different zones, and XRD and XRF were used to analyze the composition of the sample. SEM and stereo microscope were used to analyze the morphology of the sample. The results show that slagging can be divided into three processes: the formation of sodium salt precursors, the growth of silicate loose structural layers, and the adhesion of surface minerals. Temperature is selective to slagging, and the content of silicon and calcium in the sample at 873 oC is high,