铜渣熔融还原过程中硫的行为特征研究.docVIP

铜渣熔融还原过程中硫的行为特征 李磊基金项目：国家自然科学基金资助项目( 基金项目：国家自然科学基金资助项目(编号. 李磊(1986-)，男，汉族，云南昆明人，博士，副教授，研究方向为铜渣的资源化利用； 王华(1965-)，男，汉族，通讯联系人，博士，教授，研究方向为复杂有色金属资源的资源化利用，0871 E-mailwanghua65@163.com （昆明理工大学，冶金与能源工程学院，冶金节能减排教育部工程研究中心，云南省复杂有色金属资源清洁利用国家重点实验室，云南昆明，650093，中国） 摘要：对铜渣熔融还原过程中硫的行为特征进行了研究。结果表明，熔渣碱度从0.8增至1.4，渣硫容量增大脱硫作用增强，铁水硫含量由0.6%降至0.13%；铁水脱硫为吸热反应，熔渣温度由1773 K升至1823 K渣脱硫能力提升，铁水含硫由0.13%降至0.089%。熔渣-铁水硫理论分配比远大于实验时间条件下硫分配比，保温时间延长铁水脱硫率提高。熔渣碱度1.4、保温温度1823 K和保温时间 40 min时，处理后铁水含硫为0.11%，含量仍较高，需进一步对铁水进行脱硫预处理才可用于炼钢。 关键词：铜渣；熔融还原；硫行为特征；废物利用 中图分类号：TF 046 文献标志码：A Sulfur Behavior Characteristics in the Process of Copper Slags Smelting Reduction LI Lei, WANG Hua, HU Jian-hang (Engineering Research Center of Metallurgical Energy Conservation Emission Reduction, State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Ministry of Education, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, China) Abstract: The sulfur behavior characteristic in the process of copper slags smelting reduction was studied in this paper. When slag basicity increased from 0.8 to 1.4, the slag sulfur capacity and desulphurizing capacity increased, and the molten iron sulfur content decreased from 0.6% to 0.13%.Desulfurization reaction of molten iron is endothermic, and the molten iron sulfur content decreased from 0.13% to 0.089% with the holding temperature increasing from 1773 K to 1823 K. The theoretical?sulfur distribution ratio between molten slag and iron was higher than the real under the test time, and the desulfurization rates of the molten iron increased with the holding time. Sulfur content of the molten iron was decreased to 0.11% treated in the condition of holding temperature of 1823 K, residence time of 40 minutes, and slag basicity of 1.4. The iron sulfur content is still high, and the generated iron needed desulphurization pretreatment for steelmaking. Keywords: copper slags; smelting reduct