碟状颗粒的合成和球形颗粒对磷酸锆碟片液晶相变的影六响-材料工程专业毕业论文.pdf.docxVIP

广东工业大学硕士学位论文向同性相(I．I)分离，而在理论研究中球碟系统中I—1分离是否存在是具有很大争议 广东工业大学硕士学位论文 向同性相(I．I)分离，而在理论研究中球碟系统中I—1分离是否存在是具有很大争议 的，本研究的发现为球碟系统中I—1分离的存在提供了实验证据。 3．将切球模型和已有的单一碟状胶体系统的自由能表达式运用于构建由球形颗 粒和碟状颗粒组成的混合胶体的自由能密度函数(Free Energy Density)。计算了以 球为空位质的球碟混合系统的自由体积分数，发现在低厚径比碟片系统中 (，=0．0022)，碟状颗粒体积分数达到0．02的时候，自由体积分数已经趋近于零。 将上章中得到的碟状颗粒体积分数(中，)．球形颗粒体积分数(中。)的相图利用公式 巾。=a中：进行了转换，得到I{bp-中：相图，并对其进行了简单分析。 关键词：磷酸锆碟状胶体；球碟混合胶体；空位作用；液晶相变；含锰高岭石 万方数据 ABSTRACT ABSTRACT There are many mixture systems consisting of platelet colloidal suspensions and other particles in natrure and industry．In order to understand the equilibrium properties and phase state of the mixed colloidal systems and to develop soft materials with desired properties and characters，it is necessary to study the phase behavior of mixed systems consisting of platelet colloi d and other particles with different sizes and shapes．In this study,single—layer zirconium phosphate(ZrP)with uniform thickness and controllable diameter was used as template to prepare platelet colloidal system．Silica spheres were added into the colloid to study the phase behavior of ZrP platelets．Due to the significance of platelet particles in the field of research and industry,the synthesis of platelet particles was also studied．The details are listed as follows 1．ZrP crystals and platelet Mn—Kaolinite crystals were synthesized by hydrothermal method，large quantities ZrP was synthesized by refluxing method．By controlling the reaction conditions(temperature，reaction time and mole concentration of phosphoric acid)，ZrP crystals with regular shape；intact crystal type and controllable size was synthesized．The diameter range was controlled between 300 and 2000 nanometer However,the reaction temperature was up to 2000Cand the ZrP output of 1 00mL autoclave is only 49．So the reflux method of preparing ZrP was improved by using a lager stirred reactor at room temperature or relatively low temperature，and the ZrP possessed good crystal type and uniform particle size(about 25 0n