高温耐火涂层的研究—作溶胶凝胶法制备耐高温绝缘涂层.docxVIP

摘 摘 要 摘 要 本课题目的是研制出一种特殊用途的高温耐火涂层，用于金属导线的耐高温绝缘性 能，对金属导线起到保护作用，提高导线的使用寿命。该材料以正硅酸乙脂、无机盐为 先驱体，利用溶胶一凝胶法制备了高温耐火涂料，并在其组成系统中加入不同含量 Cr203，分别在60012、800C、1000C的热处理制度下，处理后制得以Cr203含量命名 的未添加Cr203、20％Cr203、40％Cr203三种高温耐火涂料样品。 分别对样品进行DTA测试，来拟定样品的烧结曲线；双曲线的分析来得知凝胶的 组成基团；通过XRD分析，来确定热处理后样品的物相组成；TGA曲线则表明样品在 热处理过程中变化的情况；利用SEM测试来观察样品在热处理前后的表面形貌以及涂 膜时，膜的结构；根据TG失重曲线，证明样品的耐高温性能；根据电绝缘性能曲线， 来研究样品的电绝缘性能； 通过对上述实验数据的分析，拟定了样品的最佳制备工艺：添加20％Cr203样品在 1000℃热处理后，烧失量仅为9％，绝缘电阻率可以达到57．71x109Q·cm。长期工作在 50℃--250℃的温度下耐高温绝缘性能良好。 关键词：正硅酸乙脂；无机盐；溶胶一凝胶；耐高温性；电绝缘性 AbstractAbstract Abstract Abstract A special fireproof dope were studied，which provide a insulation for the wire at high temperature，SO that it call bestow a protection of the metal wire，and enhance the life of the wire．The material uscs TEeS，inorganic salt as the precursor，hil曲temperature resistance insulative paints were prepared by Sol—Gel process，and Cr203 were put into the material，then three l【ind of samples withom Cr203，with 20％Cr203 and、航tll 40％Cr203 will be got after treated at the temperature of 600*C、800C、1000。C． By the DTA test ofthe sample，we can prepare the sintered curve；By analysis ofthe IR curve to confirm the radical component of the gelatin we have got：Phase composition call be confirmed through the XRD analysis；The TGA CUI-、，e Can reflect the change of the sample during the sintered process；before all after the heat treatment use the SEM test to exam the surface morphology of the sample and membrane structure when coating；According to the weightlessness CHINe，resistance to hilgh temperature ofthe sample can be proved；According to the insulated capability CHINe，insulated capability ofthe sample can be researched． By analysis experimental data，draw out the optimum preparation technology of the sample：The one谢m 20％Cr203 is merely 9％when sintered at 1000℃，and the insulated capability can reach 57．7 1 l 09Q。cm．This fireproof dope shows a superior ability of high temperature resistance insulative when works at the temperature 50℃--250℃． Key