高效znxcd1-xs光催化九半导体材料合成及性质研究.docxVIP

山东大学硕士学位论文3．2．1化合物的合成 山东大学硕士学位论文 3．2．1化合物的合成 65 3．3结果与讨论 65 3．3．1微结构表征 ．．65 3．3．2光解水制氢 ．．70 参考文献 72 致{射 75 攻读学位期间发表的学术论文和参加科研情况 ．．77 万方数据 山东大学硕士学位论文CONTENTS 山东大学硕士学位论文 CONTENTS Abstract in Chinese．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．】[ Abstract in English．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．III Abbreviation． ． ． ． ． ． ． ． ． ．． ． ． ． ． ． ．． ． VI Chapter 1 Prologue ． ． ． ． ． ． ． ． ． ． ．． ． ． ．． ． ． ．．1 1．1 Introduction ．． ． ． ． ． ． ． ． ． ． ．． ．1 1．2 Development ofZnxCdi．xS solid solution 1 1．2．1 Synthesis development ofZnxCdl．xS solid solution 2 1．2．2 Transition／alkali mental doped ZnxCdl．xS ．2 1．2．3 Control special nanostructure 4 1．2．4 Development oflow-cost cocatalyst ．6 1．3 Introduction ofPDI derivatives ． ． ． ． ．． ．． ． ． ．． ．7 1．3．1 Synthesis ofPDI derivatives ．9 1．3．2 Property ofPDI derivatives ．12 1．3．3 Application ofPDI derivatives ．．18 Reference． ．． ． ． ． ． ． ． ． ． ． ． ． ． ． ． ． ．． ．：!：； Chapter 2 Research on PDIs doped ZnxCdt．xS solid solution ．．34 2．1 Introduction． ． ． ．． ． ． ． ． ． ． ． ． ．． ． ．． ． ． 34 2。2 Experimental section．． ．． ． ． ．． ． ．． ． ．． ．． ． ． 35 2．2．1 Main instruments and reagents ．．35 2．2．2 Synthesis of compounds ．． ．36 2．3 Results and dissussion．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．42 2．3．1 Microstructure characterization 42 2．3．2 Photocatalytic splitting ofwater into hydrogen 53 2．3．3 Hydrogen production mechanism ofZn0．5Cdo．5S-PDIs 54 Reference．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．60 Chapter 3 Research on synthesis and property of Zno．5Cdo．5S／ZnS core-shell structure．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．