Al2O3纳米颗粒和微量阳离子表面活性剂CTAB协同稳定O.docVIP

第17届胶体与界面化学会议论文（摘要）集 Al2O3纳米颗粒与微量阳离子表面活性剂CTAB协同稳定的O/W乳状液 许茂东，蒋建中，崔正刚* 合成与生物胶体教育部重点实验室，江南大学化学与材料工程学院，214122，江苏无锡 *E-mail:cuizhenggang@ 通常无机纳米颗粒在水介质中是带电的，因而能够通过吸附带相反电荷的双亲化合物而被原位疏水化，变成表面活性颗粒，从而可以稳定Pickering乳状液。本文报告一种新的乳状液体系，即用表面带正电荷的纳米氧化铝颗粒与微量的带相同电荷的阳离子双亲化合物例如CTAB相结合，可以制备稳定的癸烷/水乳状液。单独采用纳米氧化铝颗粒以及浓度小于0.5cmc的CTAB都不能稳定乳状液，但用0.5%纳米氧化铝颗粒与0.01-0.5cmc的CTAB相结合作为复合乳化剂，则可以获得稳定的O/W型乳状液。显微照片和扫描电镜图像显示，纳米氧化铝颗粒并未吸附在油/水界面上，而是聚集在连续相中，形成物理障碍来阻止液珠的聚结。表面活性剂分子也不是吸附在颗粒表面，而是吸附在油/水界面，降低了界面张力，从而有利于通过均质形成乳状液。相关作用机理可以通过测定Zeta电位、界面张力以及单个液珠在油/水界面的寿命得到解释。 Fig. 1 Digital photographs of n-decane-in-water emulsions (7 mL/7 mL) stabilized by Al2O3 nanoparticles alone (A) at different concentration, by CTAB alone (B) at different concentration and by 0.5% Al2O3 nanoparticles in combination with CTAB (C) at different concentration as shown on the vessel, taken 24 h (A and B) and a month (C) after preparation. And micrographs (D and E) and SEM image (F) of the droplets stabilized by 0.5% Al2O3 nanoparticles in combination with CTAB at 0.02 mM(D), 0.6 mM (E) and 0.1 mM (F) respectively. 关键词：乳状液，协同效应，氧化铝纳米颗粒，Zeta 电位，颗粒－表面活性剂相互作用 参考文献： [1] G. Z. Li, S. E. Friberg. J. Am. Oil Chem. Soc., 1982, 59, 569-572. [2] Y. Yang, M. E. Leser, A. A. Sher, D.J. Mcclements. Food Hydrocolloids, 2013, 30, 589-596. [3] N. P. Ashby, B. P. Binks. Phys. Chem. Chem. Phys., 2000, 2, 5640-5646. [4] H. Yang, H. Zhang, J. Peng, Y. Zhang, G. Du, F. Yu. J Colloid Interface Sci, 2017, 485, 213-222. n-Decane-in-water emulsions stabilized by positively charged alumina nanoparticles in combination with trace amount of a similarly charged cationic surfactants Maodong Xu, Jianzhong Jiang and Zhenggang Cui* The Key Laboratory of synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, China It has been well known that inorganic nanoparticles are usually charged in aqueous media and can be hydrophobized in situ by adsorption of oppositely charged amphiphi