Chlorine-Char composite synthesized by co-pyrolysis of biomass wastes and polyvinyl chloride for elemental mercury removal外文学习材料.pdfVIP

Fuel 183 (2016) 73–79 Contents lists available at ScienceDirect Fuel journal homepage: www.else /l ocate/fuel Full Length Article Chlorine-Char composite synthesized by co-pyrolysis of biomass wastes and polyvinyl chloride for elemental mercury removal Yang Xu a, Xiaobo Zeng a, Guangqian Luo a,b,⇑, Bi Zhang a, Ping Xu a, Minghou Xu a, Hong Yao a,⇑ a State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China b Shenzhen Institute of Huazhong University of Science Technology, Shenzhen 518000, China h i g h l i g h t s Effects of pyrolysis temperature, mixing ratio and heating mode were investigated. Hg0 removal by Cl-Char was much higher than that by raw char (2.5–5 times). The mechanism of Hg0 adsorption was studied by XPS and TPD analysis. A novel method was proposed to synthesize Cl-Char composite for Hg0 removal. Biomass/PVC wastes are adaptive materials for synthesizing Hg0 removal sorbents. a r t i c l e i n f o a b s t r a c t Article history: A novel method using the co-pyrolysis of polyvinyl chloride (PVC) and biomass wastes (wood and paper) Received 28 January 2016 was adopted to synthesize chlorine on the surface of the char, and the synthesized Cl-Char composite was Received in revised form 2 June 2016 tested for removal of elemental mercury as a sorbent. The mercury removal efficiency of Cl-Char was Accepted 4 June 2016 much higher than that of raw char (2.5–5 times) and