具有纺锤状节点的海藻酸钙纤维的改性及其润湿性能.docVIP

具有纺锤状节点的海藻酸钙纤维的改性及其润湿性能收稿日期 收稿日期：2014-04-10 基金项目：江苏省高校自然科学研究重点项目(12KJA530002)；江苏高校优势学科建设工程项目 作者简介：纪潇波（1988-），男，山西太原人，硕士，主要研究方向为微流体技术制备功能材料；张利雄（联系人），教授，E-mail: lixzhang@njtech.edu.cn 纪潇波，孙理想，张利雄 （南京工业大学，化学化工学院 材料化学工程国家重点实验室，江苏 南京 210009） 摘要：在微流体技术制备具有纺锤状节点的海藻酸钙纤维的基础上，分别通过糠醇 (FA)，钛酸四丁酯 (TBOT)和正硅酸四乙酯 (TEOS)对其进行改性。利用傅里叶红外光谱仪（FT-IR）和扫描电子显微镜（SEM）对样品进行表征，在人造水雾中测试纤维的集水能力。结果表明：FA改性能够产生指向节点的表面能梯度，增强微小水滴在纤维上的定向聚集效应；经过TBOT改性能够让水滴在节点表面的某个区域上反重力聚集，而经过TEOS改性则让水滴在节点两端聚集。处理改性之后的节点宽度减小，向球状收缩。通过改性能够调变海藻酸钙纤维表面的能量梯度从而控制水滴润湿位置。 关键词：海藻酸钙纤维； 表面改性 ；定向聚集 中图分类号：TQ342.87 文献标识码：A 文章编号： 1671–7627（2010）00–0000–00 Modification and wetting ability of alginate calcium fiber with spindle-knots JI Xiaobo, SUN Lixiang, ZHANG Lixiong （State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing 210009, China） Abstract： Calcium alginate microfibers with spindle-knots were prepared by microfluidic technique. The microfibers Modification and properties of calcium alginate microfibers with spindle-knots calcium alginate microfibers with spindle-knots, which were prepared by microfluidic technique, were modified by furfuryl alcohol (FA), tetrabutyl titanate (TBOT) and tetraethyl orthosilicate (TEOS) separarespectivetely. The samples were characterized by Fourier transform infrared spectrometry (FT-IR), scanning electron microscope (SEM) and water collection test. The rResults showed that the FA modification generated surface energy gradient towards to knots and enhanced directional water collection effect of water droplets on the fibers. The TBOT modification resulted in aggregation of water droplets at one area of knots’ surface and antigravity. The TEOS modification led to aggregation of water droplets at both ends of knots. After modification treatment, the width of the spindle-knots decreased and shrank to globosity. These results indicated that the modification can could generate surface energy gradient to m