Degradation-kinetics-and-mechanism-of-emerging-contaminants-in-water-by-dielectric-barrier-discharge-non-thermal-plasma-The-case-of-17-Estradiol_2013_英文学习资料 .pdfVIP

Chemical Engineering Journal 228 (2013) 790–798 Contents lists available at SciVerse ScienceDirect Chemical Engineering Journal journal homepage: www.else /locate/cej Degradation kinetics and mechanism of emerging contaminants in water by dielectric barrier discharge non-thermal plasma: The case of 17b-Estradiol Lihong Gao a, Lei Sun a, Shungang Wan b, Zebin Yu a,⇑, Mingjie Li a a School of Environment, Guangxi University, Nanning 530004, PR China b Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, PR China h i g h l i g h t s Dielectric barrier discharge is effect technology to degrade 17b-Estradiol. The plasma was created at the gas–liquid interface in pulsed mode. The key parameters have significant effect on the degradation of 17 b-Estradiol. The degradation process can be described by the first order kinetic model. A possible degradation mechanism of 17 b-Estradiol were proposed tentatively. a r t i c l e i n f o a b s t r a c t Article history: A typical endocrine disrupting chemical 17 b-Estradiol (E2) in aqueous solution was decomposed by using Received 17 December 2012 dielectric barrier discharge non-thermal plasma (DBD) created at the gas–liquid interface in pulsed mode. Received in revised form 16 May 2013 The results showed the peak voltage, E2 initial concentration, initial pH value and aqueous solvent of dif- Accepted 18 May 2013 ferent characteristics have significant effect on the removal efficiency and the degradation rates of E2. Available online 29 May 2013