纳米Al2O3粉体的制备及其热稳定性的改善-矿冶工程.pdf

24 6 矿　冶　工　程 Vol.24 №6 2004 12 MINING AND M TALLURGICAL NGIN RING De ember 2004 Al O 2 3 1 1, 2 2 2 2 宋振亚, 吴玉程 , 杨　晔, 李　勇, 崔　平 (1. , 230009;2. , 230031) 　:(NH Al(SO ))(NH HCO ), ——— 4 4 2 4 3 (AACH)。 , :(300 ℃)※γ(700 ℃)※γ+θ(1050 ℃)※θ+ α(1 100 ℃)※α(1200 ℃), 1200 ℃, , “”, , SiO , SiO 2 2 , α, 。 :;Al O ;;SiO ; 2 3 2 :TQ174.6+1 :A :0253-6099(2004)06-0078-04 Preparation of Nano-sized Al O Powder and 2 3 Improvement of Its Thermal Stability 1 1, 2 2 2 2 SONG Zhen-ya , WU Yu-heng , YANG Ye , LI Yong , CUI Ping (1.School of Materials Hef ei University of Technology , Hef ei 230009, Anhui, China ;2.Institute of Solid S tate Physics CAS, Hef ei 230031, Anhui, Ch ina ) Abstract:Ammonium Aluminum Carbonate Hydroxide(AACH), as the pre ursor of α-Al2 O3, has been prepared with pre ip- itation method by using NH HCO as raw materials.During heat treatment AACH underwent su h a phase transformation pro- 4 3 ess:Amorphous(300 ℃)※γ(700 ℃)※γ+θ(1050 ℃)※θ+α(1 100 ℃)※α(1 200 ℃).But when the al ining tem- perature rea hed 1200 ℃, the alumina powder parti les with large sizewere severe sinteredwith ea h other, and many bough- like stru ture were formed in the produ ts, whi h results in great loss in the spe ifi surfa e area of Al2O3 .SiO2 was hosen as an additive to improve the thermal stability of Al2O3 powder.The results s