低软化点可溶性中间相沥青的制备.pdfVIP

2014 年第2 期 CARBON TECHNIQUES 2014№2 第33 卷 炭 素 技 术 Vol．33 ·实验研究· 低软化点可溶性中间相沥青的制备 李晓炜 ，马兆昆 ，宋怀河 ，陆彦江 ，赵永华 （北京化工大学 化工资源有效利用国家重点实验室 ，北京 100029） 摘 要：将AlCl (10%)催化萘在200 ℃恒温5 h 制得萘的齐聚物，齐聚物主要为萘的三聚体，并含有四聚体和五聚体；然后通过 3 加入不同比例的供氢剂十氢萘在340 ℃下恒温 5 h 热缩聚制得中间相沥青。 结果表明：当十氢萘加入量为 10% 时，所得的沥 青中间相含量高（100%） ，残炭率高（64.1% ） ，软化点较低（190 ℃ ） ，可溶性较强（ 甲苯可溶组分含量为60.4% ，吡啶可溶组分含 量为80.2% ）。 关键词：中间相沥青； 萘；齐聚物；十氢萘 中图分类号： 文献标识码： 文章编号： （ ） TQ314.2 A 1001-3741 2014 02-01-04 The preparation of soluble mesophase pitch with low softening point Li Xiao-wei, Ma Zhao-kun, Song Huai-he, Lu Yan-jiang, Zhao Yong-hua （Key Laboratory of Carbon Fiber and Functional Polymers ， Ministry of Education ， Beijing University of Chemical Technology,Beijing 100029 ， China ） Abstract: Mesophase pitch with low softening point has good liquidity at high temperature and is often used in impregnant for car- bon-carbon composite. In this paper mesophase pitch was prepared from the fine naphthalene using AlCl3 as the catalyst. Firstly, the oligomers were prepared from fine naphthalene at the temperature of 200 ℃ for five hours. The oligomers are mainly composed of trimer, and a small amount of tetramer and pentamer of naphthalene. Then, the mesophase pitch was obtained by adding different amount of decahydronaphthalene at the temperature of 340 ℃ for five hours. The results show that the excellent mesophase pitch with 100% anisotropic content was obtained when the addition of the decahydronaphthalen