液晶化学-11-蓝相液晶教学课件.ppt

华东理工大学 East China University of Science And Technology 蓝相液晶 按存在形态可细分为三个状态： BPⅢ——雾状 无定形 BPⅡ——简立方结构 晶格周期约 p/2 BPⅠ——体心立方 晶格周期约p 相序： BPⅢ BPⅡ BPⅠ BPⅢ Blue Phase Structures of Blue Phases I and II. The rods in (a) and (c) represent double-twist cylinder. The black lines in (b) and (d) represent disclination lines. BPIII: Structure is not clear. Model of molecule arrangements within a double-twisted cylinder polymer-stabilized blue phases Phase diagram of polymer-stabilized blue phases and schematic illustration of aggregation state of polymers Bent-core molecule stabilized blue phase The effect of end-group length on blue phase range. N*LCs host : 67.2 wt% commercially LCs + 32.8 wt% chiral material R811 Dopant: 7 wt% bent-core compound Sample Host N*LC / 93 wt% Dopant / 7 wt% TIso-BP / ℃ TBP-N* / ℃ Blue phase range / ℃ D-1 67.2 wt% NLC + 32.8 wt% R811 E-1 82.5 53.4 29 D-2 E-2 82.3 59.5 23 E-1 E-2 染料分子掺杂 synthesized four kinds of azo-dyes and doped in BP system. BP range after the doping The raise of BP range for A2 and A4 system may caused by the long conjugated structure of A2 and A4. UV controllable lattice Blue-shift of the reflective spectrum. The center wavelength shift from 623 to 539 nm. Spectra during the materials be triggered and recovered Dark recovered UV triggered Wavelength blue-shift during UV irradiation, and red-shift during recovery. Two V-shaped tendencies were found during UV irradiation and dark recovery. The V-shaped, for one thing, caused by the effect of trans-cis transforms on the pitch; for another, caused by the effect of trans-cis transforms on the orientation of the BP domain. 二相色性染料掺杂 Molecular design of dichroic Azo-dyes Similar structure with LCs the odd-even effect from the end group Red Color Two Azo One Azo ?Orange √ Dark red Improve photostability Ⅱ Decrease the dipole moment Ⅰ Introduce rigid group Solubility with LCs Large dichroism Increase the ratio of molecular length and width L