《催化剂制备原理》第五六七章加氢脱氢氧化催化剂的制备.ppt

Hydrogenation Hydrogenation of aromatics have been commercialized at a lot of plants in the world. Ni and Pt -Al2O3 is used in slurry or fixed bed reactor mostly. Ru-Al2O3 has high activity also. Hydrogenation of Benzene and Alkylbenzene A pure cyclohexane is used for raw material of nylon-6. Stable Ni or Pt-Al2O3 is commercialized as fixed bed process. Reaction condition of Ni is a little severe, 5 MPa, Pt-Al2O3 is operated 1 Mpa. The life of catalyst is 2-4 years. small amount of sulfur becomes catalyst poison. Aromatics in paraffin would be hydrogenated to naphthene and alkylcyclohexane. Small amounts of acid is promoter of the reaction. Ru-Al2O3 is excellent catalyst for hydrogenation of aromatics. Ethyl benzene is easy to be hydrogenated with Ru-Al2O3 to ethyl cyclohexane which is used none aromatic solvent. Typical reaction condition is Temp. 150℃, 1 MPa, WHSV. 1.0. Although Pd-Al2O3 has hydrogenation activity of alkylaromatics, it can not be used industry because of very sensitive to small amount of sulfur. Asahi chemical Co., developed selective hydrogenation of benzene to cyclohexene using Ru-Zn black powder catalyst in benzene-water solvent. The process was commercialized Japan and China. Cyclohexene is introduced to cyclohxanone by hydration with ZSM-5. Hydrogenation of bezoyic acid Pd-carbon powder is used for hydrogenation of benzoic acid to cyclohexane carboxylic acid which is called Sinia process producing intermediater of caprolactam. The process is commercialized in Europe and China. Hydrogenation of phenol Cyclohexanone is introduced by hydrogenation of phenol also. Cyclohexanone is raw material of nylon. Pd-carbon powder has been used at slurry bed process and Pd-Al2O3 used at fixed bed process. Modified by alkaline gives high yield. Rh or Ru gives cyclohexanol. Pt and Ni is easy to make hydrogenolysis and gives cyclohexane as follows reaction. 己内酰胺 己内酰胺是一种重要的有机化工原料，是生产尼龙—6纤维(即锦纶)和尼龙—6工程塑料的单体。 己内酰胺为白色粉末或者白色片状固体，手触有润滑感，工业品有微弱叔胺气味。纯己内酰胺的凝固点