矽型改质界面活性剂之制备及染色性研究-亚东技术学院.pdf

矽型改質界面活性劑之製備及染色性研究 Preparation and Dyeing of Modified Silicon-Based Surfactants 1 1 2 1 1 1 許家銘 黃茂全 林麗惠 王勝宏 黃俊捷 林尚明 Chia-Ming Hsu, Mao-Chuan Huang, Li-Huei Lin, Sheng-Hong Wang, Jun-Jie Huang, Shang-Ming Lin 1:亞東技術學院 材料與纖維系 2:萬能科技大學 化妝品應用與管理系 1:Department of Materials and Textiles, Oriental Institute of Technology 2:Department of Cosmetic Science, Vanung University E-mail: fc009@mail.oit.edu.tw Abstract: In this study, a series of water-soluble 前言 silicone surfactants have been synthesized by the 界面活性劑可分為親油基、連結基和親水基 reaction of Polyethylene Glycols (PEG), Maleic 三部分，溶於水後可視親油部份，解離成陰離子、 anhydride, Silanol and Fumaric acid. The structure of 陽離子、兩性離子或不解離成離子，而分為陰離子 these compounds was confirmed by using FTIR, 性界面活性劑、陽離子性界面活性劑、兩性離子性 1H-NMR and elemental analysis. The fundamental 界面活性劑和非離子性界面活性 劑等四大類。[1] properties including surface tension, foaming and 因而界面活性劑具有特殊化學結構，故具有相當高 buffer power were investigated. The experimental 的界面活性，透過降低溶液之表面張力，進而產生 results indicated that these anionic surfactants 濕潤、滲透、乳化、分散、起泡、消泡、增溶等應 simultaneously have a hydrophilic group and the 用性質，也因其構造中特殊的官能基可與介質中之 ethylene glycol-based, therefore easy to dissolve or to 各種物質產生相互作用，而可縮短加工時間、提高 disperse in water; also have reduces effect of the 產量，因而廣泛地應用於紡織、造紙、接著劑、塗 surface tension, the low foaming nature, the pH buffer 料等不同領域上。[2,3]而silicone的構造中 siloxane capacity. The dyeing ability and the leveling effect bond(Si-O)之結合能較大也較柔軟，故其表面張力 have promoted when these surfactants were used as 低，受影響溫度較小平滑性及潤滑性良好，一般常 leveling agents for cotton dyeing with direct dyes. 用在紡織加工用途上其中以整理加工用藥劑之使 Key words ：Polyethylene Glycols , Silanol , surface 用量居多。另外整理加 工用途之 Silicone ，通常為 tension