《芦苇硫酸盐法浆》-毕业设计（论文）.docVIP

PAGE l 摘 要 本文对芦苇浆经过处理后再漂白，与常规CEH三段漂进行比较，探讨少氯漂白的研究的可能性。 实验结果表明：常规三段漂的适宜条件是：C段浆浓3%、时间60min，温度25℃、pH2,E段浆浓10%、时间90min、温度60℃、pH值10,H段浆浓6%、时间120min、温度40℃、pH值7.5-8.0（终了），8g绝干浆，用氯量在8.0%，C：H=6.5：3.5时白度最高。 先进行NaNO3预处理后CEH三段漂，能达到更好的漂白效果，NaNO3预处理的最佳工艺条件为：浆浓9.0%、0.16mol/kg水NaNO3处理量26ml，0.2M的H2SO4用量0.9%，温度90℃，时间120min，卡伯值由原来的17.506下降到7.128，经处理后白度在用氯量4%升至最高为85.3%ISO，增加了10%ISO。NaNO3预处理后EH二段漂的白度达到81.3%ISO，粘度为700.8。 氧碱漂前预处理最佳条件：酸性H2O2的用量0.2%，浆浓5%，温度60℃，时间30min，pH值3。氧碱漂的最佳条件：用碱量3%，最高温度115℃，保温60min,氧压1.0Mpa，MgSO4用量0.5%,H2O2用量0.8%，浆样20g，浓度1%，漂后的粘度下降为682.8，卡伯值5.113，经氧碱漂后再CEH三段漂的白度在用氯量4.0%时增加了10.6%ISO，粘度浆至474.6ml/g。 CEpH漂白的最佳条件为：C段，E段和H段的条件与前面的常规三段漂的条件是一样的，E段中p段H2O2的用量0.8%，Na2SiO2的用量2%，MgSO4的用量0.05%，用氯量在8%时的白度比常规漂多2%ISO，粘度降低到618ml/g。 结果表明，经处理后在漂白的白度都有所增加，其中氧碱后处理的白度增加最多，但粘度下降的也最多，而过氧化氢的白度虽然增加的不是最多，但粘度下降的最少。 关键词：芦苇硫酸盐法浆，NaNO3,氧碱漂白，过氧化氢，少氯漂白 Abstract Bleaching after reed plup has been deal with,and compare with conventionality CEH three sequence bleaching,the possibility of bleaching for low chlorine has been discusscd. The results show that: the conventionality CEH three sequence bleaching with the optimum conditions of C sequence consistency of pulp 3%,time60min,temperature 25℃,pH less then 2.E sequence consistency of pulp 10%,time90min,temperature 60℃,pH more then 10. H sequence consistency of pulp 6%,time120min,temperature 40℃,pH about 7.5to8.0(ending). absolutely dry of pulp 8g, use chlorine 8%,C:H=6.5:3.5 the brightness was the best of all. If use NaNO3 deal with the CEH three sequence bleaching in advance ,the result will be obtain higher brightness. with the optimum conditions of NaNO3 deal with in advance: consistency of pulp 9%,the 0.16 mol/l NaNO3 of dosage 26ml ,the 0.2M H2SO4 of dosage 0.9%, temperature 90℃,time 120min, kappa value fall to 7.128 compare with formerly 17.506,the brightness of use chlorine 4% has been deal with attin top of 85.3%ISO,add to 10%ISO.EH two sequence bleaching after NaNO3 deal with., the brightness reach 81.2%ISO,viscosity 700.8ml/g. with the