探讨排水法收集CO2可行优越性.PDFVIP

探讨排水法收集CO 的可行优越性 2 柴国英 吴文中* （浙江省越州中学 浙江绍兴 312075） 摘要:CO 在水、饱和NaHCO 、NaCl 等溶液中的溶解量有何差异？通过对气液相平衡体系的研究 2 3 分析，利用亨利定律以及溶液中的各种平衡关系，基于计算机辅助的理论计算和相关实验，得出结论： CO 在水、NaHCO 溶液以及NaCl 溶液中的溶解量无显著差异，采用排水法收集CO 可行、优越。 2 3 2 关键词：亨利定律；二氧化碳；碳酸氢钠；盐溶液；气液相平衡 Thefeasibility andsuperiority of collectingCO withdrainage 2 method arediscussed Chai GuoyingWuWenzhong (ZhejiangYuezhou middle school,Zhejiang, Shaoxing312075) Abstract: What are the differences in the amount of CO dissolved in water and In saturated NaHCO 2 3 solution and NaCl solution? Through the system analysis of gas-liquid phase equilibrium, using a variety of balance and Henrys law and computer aided solution, theoretical calculation and experiment,conclusion: dissolution of CO in water and NaHCO solution and NaCl solution, there was no significant difference.It is 2 3 feasibleand advantageoustocollect CO with drainagemethod. 2 Keywords:Henryslaw;carbon dioxide;sodiumbicarbonate;salt solution;vapor-liquid equilibria CO 在水中溶解度更大还是在饱和NaHCO 溶液更大？有人认为，NaHCO 溶液的pH7，因此CO 2 3 3 2 － 更容易被溶解，也有人认为，NaHCO 溶液中的HCO 浓度更大(同离子效应)，使CO 更难溶解。