《ZnTiO3的性能改善技术研究》-毕业设计（论文）.docVIP

MACROBUTTON MTEditEquationSection2 SEQ MTEqn \r \h SEQ MTSec \r 1 \h SEQ MTChap \r 1 \h 学 号：201006010303  HEBEI UNITED UNIVERSITY 毕业论文 GRADUATE THESIS 设计题目：ZnTiO3的性能改善技术研究 学生姓名：康建昌 专业班级：10钢3班 学 院：冶金与能源学院 指导教师：蔡宗英 副教授 2014年6月5日 河北理工大学信息学院 摘 要 - = 2 \* ROMAN II- - = 1 \* ROMAN I- 摘 要 钛酸锌(ZnTiO3)是一种极具发展前途的微波介质材料，而主要由其生产的微波介质陶瓷主要用于用作谐振器、滤波器、介质天线、介质导波回路等微波元器件，可用于移动通讯、卫星通讯和军用雷达等方面。本文研究掺加不同量的氧化镁对偏钛酸锌ZnTiO3相合成的影响。MgTiO3、ZnTiO3具有类似的钛铁矿型晶体结构，并且Mg2+(0.072nm)的离子半径和Zn2+(0.075nm)的离子半径都非常相近，电价相同，根据形成固溶体的离子半径比原则，当比差小于15%时，两种离子可形成无限固溶体。在传统固相烧结条件下，通过对比分析在掺加不同含量MgO的条件下所制得样品XRD衍射图谱，探索钛酸锌陶瓷中各晶相间相互转变的烧结反应机理，从而找出最佳的起始原料摩尔配比和最佳制备工艺，以制备出微波介电性能优良的钛酸锌陶瓷材料。 关键词 钛酸锌；微波介质；陶瓷材料 Abstract Abstract Abstract ZnTiO3 is a very promising microwave dielectric material, which is mostly used to produce wave circuit components of resonator, filter, dielectric antenna, dielectric guided wave circuit, mobile communications, satellite communications and military radar, etc. This paper major in the influence of the generation of zinc titanate (ZnTiO3) by mixing different amounts of magnesium oxide phase . MgTiO3, ZnTiO3 has the similar ilmenite crystal structure, Mg2+?(0.072nm)?and Zn2+?(0.075nm) have similar ionic radius and?the same?price,?according to the formation of?ion?radius?solid solution?when the?ratio?is less than 15%,?two kinds of?ions?form?infinite solid solution.?In the traditional solid-phase sintering conditions, through comparative analysis under different mixing conditions MgO content of the prepared sample XRD patterns, we explore the reaction mechanism of zinc titanate ceramics sintered each crystal phases of mutual transformation, and we try to find the best the molar ratio of the starting materials and the best preparation to prepare excellent microwave dielectric properties of zinc titanate ceramic material. Keywords zinc titanate; microwave dielectric; ceramic materials 河北联合大学冶金与能源学院 目录 PAGE i