总磷_测定中高浓度铁离子干扰的消除.pdf

35 8 V ol35 N o8 2010 8 ENVIRONMENTAL SCIENCE AND MANAGEMENT Aug. 2010 : 1674- 6139( 2010) 08- 0103- 03 1 1 2 庞宏 , 于海霞 , 宋利臣 ( 1. , 154000; 2. , 150056 ) : 在测定 总磷过程中, 样品中经常含有高浓度铁离子对测定结果 生干扰根据铁离子的化学特征, 选择恰当的掩蔽剂对其掩蔽, 可以消除铁离子对测定的干扰通过对N aOH氟化钠和 EDTA 三种掩蔽剂的掩 蔽对比, 得出氟化钠掩蔽效果最好, 而且测量结果稳定, 是非常适合的掩蔽剂 : 总磷; 高干扰离子; 掩蔽剂 : X 832 : A nterference Cancellation abou tH igh Concentration ron ons in M easuring Tota l Phosphorus 1 1 2 Pang H ong , Yu H aix ia , Song L ichen ( 1. Jiam usi Environm entalM on itoring Central Station, J iamus i 154000, Ch ina; 2. H eilongjiang Provin cial Research nstitute of Environm en t Sciences, H arb in 150056, China) Abstract:The resu lts of total phosphorus awl ay sw ere interfered by h igh concen tration iron ions. A ccording to the chem ical character of the iron ion, chose the approp riate shelter reagen t and cancelled in terference of h igh concen tration iron ions. Through the contrast shelter effect of NaOH, NaF and EDTA, the result show ed that shelter effect of N aF w as the best and the m easure m ents of total phosphorusw ere stab le. So N aF w as the better shelter reagent. eywords: total phosphorus; h igh- interference ion; shelter reagent - - 4- N aOHF EDTACN P O 2 7 , N aOHF - EDTA [ 1] ,