水热法制备YAGCe纳米荧光粉.docVIP

.136.河北大学学报(自然科学版2009年 3结论 图4 YAG:Ce的透射电镜照片Fig.4TEM ima窖瞪of the fabri∞ted YAG:Ce瑚口101panlcI伪 利用水热法在有机环境下,醇、水体积比为2s 1,填充度为65%,反应温度为350℃的条件合成了YAG:Ce纳米荧光粉.掺杂的激活剂离子Ce3+对材料发光性能的影响较大,有一最佳的掺杂量.随着Ce3+离子掺杂量的增大,材料的发光强度先升高后降低,当Ce3+掺杂的摩尔分数为5%时,样品的发光强度最高.350℃条件下制备的YAG:Ce荧光粉为纯YAG相粉体,粒子呈球形,颗粒分布均匀,大小为100nm左右.参考文献: [1]马林,胡建国,万国江,等.YAG:ce发光材料合成的助熔剂研究[J].发光学报,2006,27(3:348—352. [2]丁建红,李许波,倪海勇,等.白光LED用YAG:ce”荧光粉的性能研究[J].广东有色金属学报,2006,16(1:9—11.[3]0HNo K,ABE T.Effect of BaF2on the synthesis of the single-phase cubic YAG:Tb[J].J Electrochem Soc,1986,133 (3:638—643. [4]lKEsuE A,FuRusATo I,KAMATA K.Fabrication of polycrystalline transparent YAG ceramics by a solid-state reac—tion method[J].J Am Ceram Soc,1995,78(1:225—228. [5]MIcHAEL VEn、H,sANJAY MATHuR.I∞w temperature synthesis of nanocrystalline YAG and Ce-doped YAG via d“一ferent sol—gel methods[J].J Mater Chem,1999,9:3069—3079. [6]VAQUEIR0P,LoPEQuEA M A.Influence of complexing agents and pH yttrium—iron garnet synthesized by the sol—gel method[J].Chem Mater,1997,9:2836—2841. [7]RoY suKUMAR,wANG I,1wu,SIGMUND w0LFGANG,et a1.synthesis of YAG by a citrate-nit强te combustion technique[J].Mater lett,1999,39:138—141.[8]L1Jiguang,IKEGAMI T,LEE J—H,et a1.c0-precipitation synthesis and sintering of YAG powders:the effect of precip—itant[J].J Euro Ceram,2000,20:2395—2405.[9]wANG Hongzhi,GAo Lian,NIIHANA K.synthesis of nanoscaled yttrium aluminum garnet powder by the c0_precipita—tion method[J].Mater Sci Engi,2000,A288(1:1—4. [10]TAKAMoRI T,DAVID L D.Controlled nucIeation for hydrothermal growth of yttriunl-aluminum gafnet powders[J].Am Ceram Soc,BuU,1986,65(9:1282—1286. [11]HAKuTA YuKIYA,sEINo KEzuEI,KoMlNAMI HIRosHI,et a1.synthesis of ytt“um alumina gamet by the hy— drothemal method[J].J Am Ceram Soc,1991,74:1452—1454.[12]李霞,刘宏,王继扬,等.醇一水热法制备钇铝石榴石(YAG纳米粉体[J].无机材料学报,2004,19(5:1168—1172. [13]董国义,韦志仁,李志强,等.共激活剂Br_,I一对ZnS:Mn,Cu?X发光中心的影响[J].河北大学学报:自然科学版,2001, 21(1:41—44. (责任编辑:孟素兰 水热法制备YAG:Ce纳米荧光粉 作者:李志强, 赵起, 庄云飞, 徐丽云, LI Zhi-qiang, ZHAO Qi, ZHUA