交联卡拉胶制备工艺研究.docxVIP

交联卡拉胶制备工艺研究 摘要主要研究了不同浓度的卡拉胶溶液浸泡到不同浓度氯化钥溶液中形成离子交联卡拉胶力学性质和物理化学性质，用单因素法确定最佳的实验条件：6. 0%t -卡拉胶，7%BaCL溶液，在该实验条件下得到离子交联卡拉胶的拉伸强度为4. 54 N,断裂延伸率为59. 26%,提高了卡拉胶耐热性和耐酸性。还研究了 3. 0% i -卡拉胶在加入6. 25%环氧氯丙烷作为交联剂，在90°C , pH10. 0的条件下反应2h之后浸泡到不同浓度氯化钥溶液中形成环氧氯丙烷交联卡拉胶力学性质和物理化学性质，用单因素法确定最佳的实验条件：7%BaCL溶液，在该实验条件下得到环氧氯丙烷交联卡拉胶的拉伸强度为4.32 N,断裂延伸率为26. 01%,提高了耐热性和耐酸性。最后，实验制备2. 0% i -卡拉胶不交联,不共混条件下，得到纯卡拉胶胶；2. 0%t -卡拉胶分别与不同浓度海藻酸钠和不同浓度PVA的共混膜,分析了纯卡拉胶膜和共混膜的力学性质和物理化学性质，2%卡拉胶和1. 5%海藻酸钠是最佳配比，制备的共混膜弹性最好，拉伸断裂强度达到为27. 01 N,断裂延伸率也达到最大值为15. 94%； 2%卡拉胶和0. 5%PVA是最佳配比，制备的共混膜弹性最好,拉伸断裂强度达到最大值为24. 87 N,断裂延伸率也达到最大值为26. 41%。纯卡拉胶和两种共混膜都溶解于80°C热水，都有较好的耐碱性；纯卡拉胶溶于酸性溶液，而共混膜微溶于酸性溶液，共混后提高卡拉胶的耐酸性。 关键词卡拉胶交联共混膜 Study on Preparation of Cross-linked Carrageenan System Abstract Mainly studied the soaking in carrageenan solution with different concentration todifferent concentrations of barium chloride solution formed ion cross-linked carrageenanmechanical properties and physical and chemical properties, using single factor method todetermine the optimal experimental conditions: 6.0% iota carrageenan, the solution of 7%BaCI.Under the experimental conditions are the tensile strength of the ion cross-linked carrageenan4.54 N,breaking elongation rate was 59.26%, improve the carrageenan heat resistance and acidresistance. Also studied the 3.0% iota carrageenan before joining 6.25% epichlorohydrin ascrosslinking agent, at 90 °C,under the condition of pH 10.0 2h after soaked to the differentconcentrations of barium chloride solution epichlorohydrin cross-linked carrageenan mechanicalproperties and physical and chemical properties, using single factor method to determine theoptimal experimental conditions: solution of 7%BaCL Under the experimental conditions obtainedtensile strength of epichlorohydrin cross-linked carrageenan 4.32 N, breaking elongation rate26.01% and improve the heat resistance and acid resistance. Finally, experimental system by2.0% iota carrageenan without crosslinking, blending condition to o