毕业设计：微晶透明熔块釉的析晶机理及其控制方法.docVIP

PAGE PAGE II PAGE PAGE III PAGE PAGE I 微晶透明熔块釉的析晶机理及其控制方法 摘 要 普通透明熔块釉具有烧成温度低、釉面光泽度和透明度良好的优点，但是普遍存在的问题是硬度较低，一般为维氏硬度5000~5200MPa。微晶透明熔块釉改善了普通熔块釉釉面硬度偏低的不足，而釉中微晶体的产生情况对釉面性能有着重要的影响。 为了研究透明微晶熔块釉中微晶的析出机理及析晶控制方法，实验使用钾长石、硼砂、硼酸、滑石、碳酸锂、碳酸钙、氧化锌、碳酸钡、碳酸锶、氧化镧、氢氧化铝、石英和硅酸锆为主要原料，利用单因素调节法和正交实验方法，对多个配方因素进行调整，同时改变釉烧温度制度，制备了透明玻璃熔块。加入添加剂和水经过球磨，得到二次烧成用低温熔块釉。利用硬度测试仪、XRD、SEM等手段进行测试，对检测结果进行分析，探讨了化学组成和釉烧制度对透明微晶熔块釉微晶析出情况和釉面质量的影响。 结果表明，同一釉烧温度下，随着ZrO2含量的增加，釉面结晶度和硬度呈现先增后减的趋势，Li2O含量的增加时，熔块釉釉面析晶度和硬度变化也是先增后减，B2O3对熔块釉中ZrSiO4的析晶有抑制作用；原料对釉面的影响程度，按照硅酸锆，碳酸锂，碳酸钙，硼砂，钾长石，石英，硼酸顺序排列；釉中晶体的析出程度随温度的升高而增强，随保温时间的延长先增强后减弱；釉面硬度的变化与析晶度一致，析晶程度过大使釉面透明不好；根据实验结论改变釉料配方或釉烧温度制度，可以控制釉面析晶的数量和尺寸，改善釉面质量。 关键词：微晶，透明釉，析晶，控制  Crystallization Mechanization and its Controlling Method of Microcrystalline Transparent Fritted Glaze ABSTRACT The ordinary transparent fritted glaze have low firing temperature, high gloss and good transparency, while the common problem is the low hardness. Mirocrystalline transparent fritted glaze improves the deficiency of ordinary fritted glaze. And the situation of microcrystal appearance in fritted glaze has a significant impact on glaze property. In order to study the mechanism controlling methods of precipitation of microcrystal in microcrystalline transparent fritted glaze, the experiment take potassium feldspar, borax, boric acid, talc, lithium carbonate, calcium carbonate, zinc oxide, barium carbonate, strontium carbonate, lanthanum oxide, aluminum hydroxide, quartz and zirconium silicate as the main raw material, use the single factor experiment and orthogonal experimental method to adjust multiple formula factors, while changing the glaze firing temperature schedule, to prepare transparent glass frit. Adding additives and water during ball mill, low temperature fritted glazes by twice sintering process are obtained. Using hardness tester, XRD,SEM to test the glaze, analyze the test result, and discuss the impact of chemical composition and the glaze firing temperature schedul