原子、分子在强激光场中的一些现象.pptVIP

原子、分子在强激光场中的一些现象 背 景 光电能谱 离子动能谱 高次谐波 展望与问题 强激光场 Multi-photo processes (Above threshold ionization) 量子效应 非线性光学效应 Tunneling ionization 强激光场 Multi-photo processes (Above threshold ionization) 量子效应 非线性光学效应 Tunneling ionization Photoelectron Spectrum for H 228 nm, 16-cycle laser 1.7×1014 W/cm2 K. Burnett et al., PRA, 51, 4824(1995) R. Wiehle et al., PRA, 67, 063405(2003) Photoelectron Spectrum for Ar 800 nm, 100fs, 4.6-5.4×1013 W/cm2 H. Figger et al., PRL, 94,163002(2005) M.F.Kling et al., Science,312,246(2006) for H2+ 791 nm, 100fs, 1×1015 W/cm2 Floquet dressed potential Vibrationally resolved kinetic-energy spectrum for H2+ 791 nm, 100fs, 8.8×1013 W/cm2 H. Figger et al., PRL,94,163002(2005) B. D. Esry et al., PRL, 97,013003(2006) Experiment Theory for H2+ 790 nm, 45fs, 2.4×1014 W/cm2 I.Ben-Itzhak et al., PRL, 95, 073002(2005) for H2+ 800 nm, 25fs, 2×1014 W/cm2 B.Feuerstein et al., PRA, 67, 043405(2003) ? 1D calculation (critical approximation) Control the movement of nucleus From the PPT file of A. Stolow in Xth National Chemical Dynamics Symposium Control the localization of electron M.F.Kling et al., Science,312,246(2006) for D2+ 760 nm, 5fs, 1×1014 W/cm2 Three-step (semi-classical theory): 1. Field tunnel ionization of electron (initiation) 2. Electron oscillate in laser field (accelerate) 3. Electron re-collide with ion (recombines) Step 1 Step 2 Step 3 P.B.Corkum, PRL, 71, 1994(1993) 产生机制 Step 1 Step 2 Step 3 由某一基频光与非线性物质作用而辐射出一系列的频率是基 频光整数倍的光。 (VUV, EUV, soft and hard X-ray) The contribution to the evolution of the system of all bound states except the ground state can be neglected. (b) The depletion of the ground state can be neglected. (c) In the continuum, the electron can be treated as a free particle moving in the electric field with no effect of Coulumb potential. Quantum mechanical explanation M. Lewenstein et al. PRA, 49, 2117(1994) 研究目的：展宽谐波平台及提高高次谐波产生效率 展宽谐波平台 增加电离势 增加有质电动势 1、 2、附加静电场、静磁场 两平台 提高高次谐转化效率 选择在高能区具有较强连续态－基态耦合强度的体系 采用