离子液体在废水处理中应用研究.docVIP

PAGE / NUMPAGES 摘 要 离子液体是一种在室温或接近室温下呈液态、完全由离子组成的化合物，又称室温离子液体或室温熔盐，简称离子液体。其常作为绿色溶剂和催化剂应用于有机合成中，其良好溶解性也可作为萃取剂应用于废水处理中。 本文系统介绍了离子液体的种类、结构、性质、制备方法以及在废水处理方面的应用。并通过微波两步合成法合成离子液体[Omim]PF6，然后对离子液体[Omim]PF6进行表征，最后用离子液体[Omim]PF6萃取模拟焦化含酚废水中的苯酚，通过实验得到结论：在相比取V离子液体:V含酚溶液=1:1.5，萃取反应时间控制在30min，反应温度设定为20℃以下，含酚溶液pH值小于7，微波反应40s时获得的萃取率最高，并且离子液体[Omim]PF6作为萃取剂其再生性良好，可以实现循环利用。 关键词：离子液体，废水处理，萃取 ABSTRACT Ionic liquid is a liquid at room temperature or near room temperature show, entirely composed of ion compound, also known as room temperature ionic liquids or room tempera -ture molten salts, referred to as ionic liquids. The often used as a green solvent and catalyst used in organic synthesis, its good solubility and can be used as extracting agent used in wastewater treatment. Type of ionic liquid are introduced in this paper, system, structure, properties, preparation methods and application in wastewater treatment. And through two steps of microwave synthesis [Omim] PF6, synthesis of ionic liquids and the ionic liquid [Omim] PF6 were characterized, and the ionic liquid [Omim] PF6 extraction was used to simulate coking phenol in waste water containing phenol, come to a conclusion: through the experiment in ionic liquid than take V：V = 1：1.5, phenol solution extraction reaction time control in 30 min, reaction temperature setting as below 20℃, phenol solution pH value is less than 7, the microwave reaction 40 s to get the highest extraction rate, and ionic liquid [Omim] PF6 as extraction agent the reproducibility is good, can realize recycling. KEY WORDS: Ionic liquid,Wastewater treatment,extraction 目 录 TOC \o 1-3 \h \z \u 4081 第1章 绪论 1 24480 1.1 研究背景 1 9227 1.2 目的与意义 1 23958 1.3 国内外现状 2 30976 1.4 论文的主要内容、方法及技术路线 3 31056 1.4.1 论文的主要内容、方法 4 16547 1.4.2 论文主要研究技术路线 4 4627 第2章 离子液体的种类、结构及性质 5 26361 2.1 离子液体的种类 5 3673 2.2 离子液体的结构 6 24819 2.3 离子液体的性质 7 7718 2.3.1 离子液体的熔点 7 23031 2.3.2 离子液体的溶解性 8 21749 2.3.3 离子液体的热稳定性 8 32410 2.3.4