2线型缩聚物的分子量与分子量分布.pptVIP

2线型缩聚物的分子量与分子量分布;Factors Influence on the Molecular Weight;Closed system： = + 1 ; Self-Catalyzed system： = 2k3 t + 1;With the same mole ratio of groups ：;Key: Deactivation of the functional end groups, i.e., stabilization of molecular weight;For the systems of a-R-a + b-R‘-b, not a-R-b ; a-R-a b-R-b ;大家学习辛苦了，还是要坚持;The total of macromolecules ;Thus ; Theoretically, if the mole ratio of the two functional groups in the systems of a-R-a + b-R‘-b can be kept equal，the average degree of the condensation polymer will reach the maximum to the end of reaction.;The Excessive percentage q of b-R‘-b molecule is often used besides r. The q is defined as: ;R-b can react with group a in the polymer. By this method, the end groups are captured, giving the stabilized molecular weight. The molecular weight of polymer can be adjusted by R”-b. This method can be used for both the system a-R-a / b-R’-b and the system of a-R-b. ;① The systems of a-R-a + b-R‘-b with  the same mole ratio;② The system of a-R-b; The high purity of monomer Precise measurement Proper temperature control Protected by inert gas, along with using catalytic agent and vacuumizing the system