间隙位置Tetrahedralposition四面体位置Octahedralposition八面体.pptVIP

Ceramic Materials Structures and Properties  Ceramic Materials陶瓷材料 Inorganic materials無機材料 Nonmetallic materials非金屬材料 Most ceramics are compounds between metallic and nonmetallic elements Composed of at least two elements and often more Atomic bonding in ceramics ranges from purely ionic to totally covalent  ionic character=1-e Material lonic Character CaF 89% Mgo 73% Nacl 67% Al2O 63% 51% SiN 30% Zns 18% SIC 12%  Electronegativity電負度丶陰電性 IIIA IVA VA VIA VIIA 1.01.5 202.53.03.54.0 AI SiPSCIA 091.2|Ⅲ B VB VB VIB VIIB B|B151.82.12.530 K Ca Sc Tiv Cr Mn Fe Co Ni Cu Zn Ga Ge As Se BrKr 081.01.31.51.61.61.51.81.81.8191.61.6182.02428- Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn SbTe 181.92.12.5 Cs Ba La-Lu Hf Ta W Re Os Ir Pt Au Hg TI Pb Bi Po At Rn 0709 2131.5171922222224191818192022 Fr Ra Ac-No  Stable and unstable cation-anion coordination configuration 883 stable stable unstable Cations are ordinarily smaller than anions cation陽離子 anion陰離子  Coordination Number配位數 Coordination Number配位數 2 3 6 8 89争8 Cation-Anion Radius Ration 0!50.155-0.2250.225-0.4140.414-0.7320.732-1  rc/A1→配位數12  Crystal Structures AX Type - Rock Salt Structure岩鹽結構 Cesium chloride structure氯化铯結構 - Zinc Blende( Sphalerite) Structure閃鋅礦結 構 AX Tvpe Fluorite Structure螢石結構丶氟石結構 ABX3 Type Perovskite Structure鈣獄礦結構 AB2X4 Type - Spinel structure尖晶石結構  Rock Salt structure岩鹽結構 Nacl, Mgo, MnS, LiF, FeO +=0.102nm rc-=0.181nm INat/rcr=0.564  Cesium Chloride structure 氯化鉋結構 CsC s+=0.170nm r1-=0.181nm rc+/re-=0939 Cst