Co_Zn-ZIFs杂化物的制备及其对聚合物阻燃性能的影响.pdfVIP

与膨胀型阻燃添加剂(IFR)复配后添加到TPU 中。通过TGA、LOI、UL94、CONE 和TG-IR 等研究了Co-ZIF-L@RGO 和IFR 复配对TPU 复合材料热性能、阻燃和抑 烟性能的影响，并且还探究了复合材料的导热性能。CONE 结果显示，TPU 复合材 料的pHRR、THR、pSPR 和TSP 分别降低 84.4%、70.1%、60.3%和 62.5%，32.6% 的LOI 值也表面TPU 的火灾安全性得到了提高。这是因为该杂化物和IFR 的协同 作用促进膨胀的炭层变得致密，更好的改善了TPU 的阻燃抑烟性。此外，阻燃抑烟 机理也进行了详细地讨论。 图 [50] 表 [15] 参 [116] 关键词：沸石咪唑酯骨架材料；杂化物；复合材料；阻燃；抑烟 分类号：TQ317 II Abstract In recent years, Zeolitic Imidazolate Framework materials (ZIFs) have received attention in the fields of catalysis and adsorption, as well as research in the field of composite materials. However, some researchers have found that ZIFs have limited flame retardant and smoke suppression effects on EP, and are prone to agglomeration andpoor dispersion in EPmatrix.In order to solve theseproblems,ZIFs were modified in this work, several nano-hybrid materials were prepared, and their effects on the thermal performance, flame retardant and smoke suppression properties of composites were studied. Firstly, by electrostatic adsorption, ZIF-8 and ZIF-67 nanoparticles were deposited on the surface of β-FeOOH nanorods. Then, ZIF-8-β-FeOOH and ZIF-67-β-FeOOH nano-hybrids were added to the EPmatrix through a simple blending method to explore its effect on the flame retardancy and smoke suppression of EP. Secondly,in thispaper,TEOSwas coated with SiO on the surface ofZIF-67-β-FeOOH 2 by hydrolysis and addedtoEPto explore its effect on improvingthe flameretardant and smoke suppression properties of EP. Finally, this article also uses the synergistic flame retardant effect of Co-ZIF-L@RGO and IFR to explore the optimal synergistic ratio of the two and its effect on the flame retardant smoke suppression performance and thermalconductivity ofTPU. (1) Two nano-hybrids of ZIF-8-β-FeOOH and ZIF-67-β-FeOOH were prepared to improve the flame retardant and