有机化学-第六版-第04章-芳香烃.pptVIP

Benzene Hückel Theory Benzene Pz Wave Functions A molecule is aromatic only if it has a planar, monocyclic system of conjugation and contains a total of 4n + 2πelectrons, where n is an integer (0, 1, 2, 3, ..). Frosts Circle (Polygon Rule) p MOs of Benzene Bonding Antibonding Frosts Circle (Polygon Rule) 6 ? es 6 ? es 8 ? es 2 ? es 4 ? es 6 ? es ?-MOs of Benzene Benzene 6 p orbitals give 6 ? orbitals. 3 orbitals are bonding; 3 are antibonding. Antibonding Bonding Benzene Antibonding Bonding 6 ? electrons fill all of the bonding orbitals. All ? antibonding orbitals are emp