浙江大学有机化学(丙)试题库(完成反应2).docxVIP

可编辑 可编辑 CH2=CHCH2CHO + CH20H I CH2OH HCl(g) w KMnO 4/OH H2O + CHjMgl H2O r.t 稀OH 2CH3CHO —— CHO浓碱5 一 CHO 浓碱 + HCHO OCH3 6 CH3CH2COCH3 + |2/NaOH 7 CHO ◎ + 2Ag(NH3)2OH 飞 8 一 10 CHO NaBH4 - H2O 乙醇” H2O CH2CCH3 + Br2/NaOH O 11 CHO + HCHO （过量） CHO 浓碱 12 OH CH2CCH3 II O Zn -Hg 1- HCl 13 CH3 「CHsCHMgBr CH3CH2CHO + ? 2. H3O 14 （用Fischer式表示）A （用Fischer式表示） A CHO HCN H | OH CH2OH OH 16 h h2o （CH^CMgBr + CO2 18 CH3CHCH2CH3 I  NaOH/b ——# CH2CHO 1.CH3CH2MgBr 2. H3O+ H2SO4 * △ 21 H2N—NH2,0H「 DMSO,高温 O CH3 1. LiAlH4 2. H2O 22 才、~CHCHO Fehing . CH3 CHO 2325oH/NNaOHH2O巴262 CH 30HCH 2CHOCH 23 25 oH/N NaOH H2O巴 26 2 CH 30HCH 2CHO CH3 稀OH 27 CH2CHO (C6H5)3P=CHCH(CH 3)2 28 CH3 NH CH3 NH3 CH2CHC00H NaOH/Br2 ? A 29 Tollensf^VCHCHO Tollens \TCh3 CHO 30 O 1. CH3CH2ONa CH3C—OC2H5 - 2.H+ 31 CH2CH2CH2COOH I OH CH2COOH Br2/NaOH ? 34 PAGE # PAGE # 可编辑 CH2CH2COOH I i CH2CH2COOH △ CH2CH2COOC2H5 1.CH3CH2ONa CH2CH2COOC2H5 2.H+ 37 OHO O+ OH O O + CHbCoCcH? H2S°4 38 CH2CI1C=o CH2CI 1 C=o eg HCN + H3O △ NaCN ? EtOH + H3O ?■ A 39 0 0 CH3COCCH3 + NaAc ” △ 可编辑 可编辑 CH3 CH3CHCH2COOH + NaHCO3 41 CH3 CH3CHCH2COOH + PC3 42 O CH3CH2OH O 43 稀OH 稀OH H2O - 44 (CH3) (CH3)3CCOOH SOCl2? 吡啶 45 ^~^COOH SOCb. ^~^COOH SOCb. (CH3)3COH ” 吡啶-” 46 N I H PAGE # PAGE # 可编辑 47 CHQ O — C-Br + ” -OH Na。* 48 O O + 2NH3—? Sr 3 O 49 I.CHQNa 2. CHd + H3O CH2CH2COOC2H5 CH3CH2ONa CH2CH2CH2COOC2H5 - 51 KMnO 4/H+ * A CH 3 NaNO2 H2SO4 0 C H3PO2 ■ 52 NH2 0 NaNO2 H2SC4 0 C PAGE # PAGE # 可编辑 NH2 NaN02 H2SO4 OC C12CI2 HCl 54 NaNO2 HCl 0 C N(CH 3)2 + 55 NO2 OFe/HCI 1—C CH3COCJ 吡啶? 56 CH3 SO2CI NHCH3 57 + HNO2 —* 58 Br2(H2O) I + CHsCOCI AICI3 无水 12/NaOH ? △ 66可编辑 66 可编辑 60 CH3 NaOH/B々 CH3CHCH2CONH2 2 △ 61 goci h2nconh2 —(酮式)（烯醇式）Ch2 h2nconh2 —(酮式) （烯醇式） Coci 62 N2Cl N2Cl 山+ CH3 63 CH3 CH3CH2CH2CHO + (CgH5)3P=CCH2CH3 64 7A3 3F cl cl cl 7 A 3 3 F cl cl cl PAGE # PAGE # 可编辑 67浓 NaOHA+ KNO 3/H2SO4(SOs) 300NH3 67 浓 NaOH A + KNO 3/H2SO4(SOs) 300 NH3 (液) + KNH 2 CH2CH3 + HNO3 70 + KNO 3/H2SO4(SO3)— Fe/HCl ? △ 71