化学原理课件-英文课件-5+Chemical+bonding.pptVIP

20XX年复习资料;Molecular Structure: Chemical Bonding and Theory;Valence electrons are the outer shell electrons of an atom. The valence electrons are the electrons that participate in chemical bonding.; 1. How to distinguish covalent bond from ionic bond ;Electronegativity is the ability of an atom to attract the electrons toward itself in a chemical bond.;Classify the following bonds as ionic, polar covalent, or covalent: The bond in CsCl; the bond in H2S; and the NN bond in H2NNH2.;Lattice energy (U) increases as Q increases and/or as r decreases.;Born-Haber Cycle for Determining Lattice Energy;Comparison of Ionic and Covalent Compounds;covalent bond parameters;(b) Bond energy: the enthalpy change required to break a particular bond in one mole of gaseous molecules.;(C) Bond angle: the angle between two adjacent bonds.;Predict molecule geometry, based on the electrostatic repulsions between the electron pairs (bonding and nonbonding).;Geometry of ABx molecules and ions in which A has no lone Pairs;SN;;Dipole Moments and Polar Molecules;10.2;10.2;10.2;Does CH2Cl2 have a dipole moment?;10.2;+; 5 Valence Bond Theory and Hybridization of Atomic Orbitals;N – 1s22s22p3;CH4;Hybridization: mixing of two or more atomic orbitals to form a new set of hybrid orbitals.;sp;N – [He]2s22p3;SF6;2021/3/18;;Benzene;the bonds are formed by molecular orbitals, which results from the interaction of atomic orbitals in the molecule.;Paramagnetic;Application of Schr?dinger to Hydrogen Molecule ;Li 1s2 2s1;bond order;Two possible interaction between two p orbitals:;2021/3/18;LUMO ;Exercises: 9.73 9.120 10.10 10.24 10.37 10.88 ;相信梦想是价值的源泉，相信眼光决定未来的一切，相信成功的信念比成功本身更重要，相信人生有挫折没有失败，相信生命的质量来自决不妥协的信念。