用作染料敏化太阳能电池对电极的性能.docxVIP

Abs仃actAbstract Abs仃act Abstract Dye—sensitized solar cell fossc)is a light-to-energy conversion device which has attracted great attentions largely because of their low—cost，hi}gh-efficiency，simple preparation method，and environment—friendly．Traditionally，DSSC is composed of a dye-sensitized photoanode，a counter electrode and an electrolyte．As one of the most critical components of DSSC，the main function of CE was collected electrons from external circuit and catalyzed the reduction of 13’to I。in the electrolyte．Therefore， this requires that the ideal counter electrode materials must possess hi曲electrical conductivity and excellent catalytic activity．Pt is an ideal CE material which possesses high catalytic activity and electrical conductivity．However，as one of the expensive and scarce resources Pt is not suitable for the large—scale application in DSSC．To overcome this problem，it is necessary to exploit the platinum alternative with high efficiency，low cost，and stable characteristics．So far，several low-cost materials have been developed as the platinum alternative materials，such as carbon material， conductive polymers，transition-metal compounds and composites．However，those CE materials also have their limitations．For example，sulfides are poisonous，noble metals are scarce and the fabrication methods of conductive polymers are complex． Therefore，in this work we try to find a CE material with low-costhi．gh efficiency， good stability，no toxicity and simple fabrication． The chemical elements of perovskite-type oxides widely exist in the periodic table． In recent years，perovskite-type oxides have attracted great attention and have been extensively research due to their interesting physical properties，such as ferroelectric properties，electrical conductivity，magnetic properties and catalytic performance，etc． As one of important member in perovskite family，La0．678r0．33M．n03(LSMO)and La0 5Sr0．5C003(LSCO)have attracted a lot of interest and have been extensively applied in