现代无机化学进展课件参考文献2-tiling.pdf

Nets and Tiling Michael OKeeffe Introduction to tiling theory and its lication to crystal nets Start with tiling in two dimensions. Surface of sphere and plane Sphere is two-dimensional. We require only two coordinates to specify position on the surface of a sphere: The coordinates of Changchun 43.9 N, 234.8 W Tempe 33.4 N, 121.9 W As far as we are concerned Tilings in two dimensions are edge-to-edge (each edge is common to just two tiles) In three dimensions face-to-face (each face common to just two tiles) Three different embeddings of the same abstract tiling brick wall honeycomb herringbone c2mm p 6mm p2gg Again, two embeddings of the same abstract tiling double brick Cairo tiling Both h e same symmetry, p 4gm . The Cairo conformation is the minimum density for equal edges. Recall Steinitz theorem Planar 3-connected graph is graph of a convex polyhedron 33 34 43 35 53 Tilings of the sphere (polyhedra) - regular polyhedra. one kind of vertex, one kind of edge, one kind of face 3.4.3.4 3.5.3.5 Quasiregular polyhedra: one kind of vertex, one kind of edge Tiling of the plane - regular tilings one kind of vertex, one kind of edge, one kind of face 36 44 63 hexagonal lattice square lattice honeycomb net quasiregular one kind of vertex, one kind of edge 3.6.3.6 kagome net honey comb net is not a lattice A lattice is a set of points related by translations honeycombnet is actually a lattice complex - a set of symmetry-related points related by translations cubic Archimedean polyhedra