国内硅酸盐长余辉发光材料的制备与研究展望.docVIP

国内硅酸盐长余辉发光材料的制备与研究展望 摘 要 光—世界因此而绚丽多彩。发光材料的开发与应用正深刻而美好的改变着我们的生活。作为固体发光材料中很重要的一类，长余辉发光材料的研究早在19世纪70年代就己经开始。随着社会的发展与进步，对这类材料的发光性能要求也不断提高。 20世纪90年代制备出的新一代长余辉发光材料因具备更佳的发光性能而倍受关注，一直是研究的热点。目前，研究主要集中在铝酸盐体系，对硅酸盐体系的研究较少。而硅酸盐体系化学性质较铝酸盐体系稳定，具有更好的适应性，但硅酸盐体系的发光性能尚未达到铝酸盐体系水平，进一步提高硅酸盐体系的发光性能，还需做更深入的工作。 本文综述了长余辉材料的发展、现状，着重阐述了硅酸盐长余辉发光材料的发展、现状、制备方法和应用前景。 关键词：硅酸盐；长余辉；发光材料；合成方法；展望 Abstract It is light that the world is flowery and colorized．The research and applications of luminescent materials have changed our lives importantly and admirably. As one of the most important state luminescent materials，the long after glow phosphors had been researched as early as 70s of 19 century．With the development and progress of society，the requirement of these materials is boosting． In 1990s，the new long afterglow phosphors were synthesized，and were attended especially because of their better luminescence properties．At present the research is focused more on the system of aluminate than silicate．The silicate is more stable than the aluminate，and have better adaptable，but its luminescence properties do not achieve aluminates．There a lot of work must be done for improving the luminescence properties of silicate． In this paper，the current situation，development，characteristic of phosphors，preparation and application prospect of silicate long afterglow luminescent materials were summarized． Keywords：silicate；long afterglow；luminescent materials；synthesis methods； prospect 目 录 TOC \o 1-3 \h \z \u 摘 要 i Abstract ii 1 引言 1 2 硅酸盐系长余辉发光材料研究动态 1 2.1 二元硅酸盐体系 1 2.2 三元硅酸盐体系 2 3 硅酸盐系长余辉发光材料的制备 3 3.1 高温固相法 3 3.2 溶胶－凝胶法 4 3.3 燃烧法 4 3.4 共沉淀法 5 3.5 微波合成法 5 4 硅酸盐长余辉发光材料的研究展望 6 [参考文献] 6 致 谢 10 1引言 硅酸盐系长余辉光致发光材料具有良好的化学稳定性和热稳定性，其发光颜 色与铝酸盐系长余辉发光材料可以互补，且在某些行业如陶瓷行业应用好于其它类长余辉发光材料[[] [] 姜岭, 常程康, 毛大立. 长余辉发光材料的研究进展[J]. 无机材料学报, 2004, 19 (2): 268-273 硅酸盐系[[] Xiao Z G, Tang M D. Fluorescence and Energy Transfer In BaMg [] Xiao Z G, Tang M D. Fluorescence and Energy Transfer