钙钛矿太阳能电池全英文介绍.pptxVIP

Short Overview of Perovskite Solar CellsNew Promising Materials for Next Generation Solar CellsHadi Maghsoudi27 February 2015Slides at: /hadimaghsoudi/perovskite-solar-cellsBasic Structure of a Photovoltaic Solar CellA photovoltaic solar cell is made of three main part: Light Absorber; converting incident photons to electron and holesCarrier Collector/s; capturing the carriers Metal Contacts: transferring the carriers to the circuitThe heart of a solar cell is the absorber layerBasic schematic of a photovoltaic solar cellThree Generations of Solar CellsHighest efficiencyWafer based: Monocrystalline silicon 25%Polycrystalline silicon 20%Multi-junction cell (different band-gap materials) 40%Thin Films:Amorphous thin film silicon 13%CdTe (Cadmium Telluride) 17%CIGS (Copper Indium Gallium Selenium) 20%Low Cost and high Efficient:DSSC (Dye-sensitized solar cells)QDSSC (Quantum Dot-sensitized solar cells) OPV (Organic photovoltics)QDs-Polymer Hybrid solar cellsPerovskite Solar CellsEmergence of Perovskite Solar CellsEfficiency jump in photovoltaics researchFrom 3.8 % in 2009 to 15.9 % in 201415% perovskite solar cell made in University of OxfordScience 18 October 2013: Vol. 342 no. 6156 pp. 317-318Superiorities of Perovskite Solar CellsHigh efficiency; with an efficiency of 15.9% after only several years work.Facile low temperature solution-based fabrication method; High absorption coefficient.Higher stability in air.High diffusion length, high charge-carrier mobilities.it means that the light-generated electrons and holes can move large enough distances to be extracted as current, instead of losing their energy as heat within the cellvery high values of open-circuit voltages (VOC) typically obtained.Perovskite Crystal StructureUsually have stoichiometry of AMX3 X is an oxide or halide anion such as Cl, Br and I. M refers to a metal cation with a coordination number of 6.The MX6 octahedra share corners and A is usually a large