化学镀铜液的制备及其在高分子基材上的应用.docVIP

PAGE PAGE 32 化学镀铜液的制备及其在高分子基材上的应用 摘要 化学镀是在无外电流通过的情况下,利用还原剂将电解质溶液中的金属离子化学还原在活性催化的材料表面上,沉积出与基体牢固结合的镀覆层。本文研究了PET和PVC高分子基材上的化学镀铜。考察了粗化、敏化、活化、温度、PH等条件对镀铜效果的影响，结果表明预处理中粗化、敏化、活化过程的温度、时间和溶液的浓度对镀铜效果都有不同程度的影响，粗化的最佳温度为345K，最佳时间为20min；敏化温度对镀层的影响不大，敏化过程的最佳时间为5min，活化过程的最佳时间为5min。PET镀铜随温度的升高，镀铜的效果也逐渐提高，当温度达到70℃时，镀铜效果降低，PVC镀铜随着温度的升高，镀层的效果也逐渐升高，当温度达到65℃时，镀铜效果降低；PET镀铜的最佳pH为12，PVC镀铜的最佳pH为11。化学镀铜反应中，主盐和还原剂的浓度对镀层也有很大的影响，硫酸铜的最佳质量浓度为 关键词化学镀铜；工艺技术；高分子材料；影响因素 Preparation of Electroless Copper Plating Solution and its Application on Polymer Material Abstract Electroless plating was used to restore the metal ion in the electrolyte solution on the surface of the active catalyst by means of the reducing agent, and the coating layer was deposited on the surface of the substrate. This topiconstudy on PET and PVC polymer substrate through electroless copper plating . The study focus on effects of roughening, sensitization, activation, temperature, pH and conditions of copper effect. Results show that pretreatment roughening, sensitization, activation time and solution concentration can affect the plating effect. The results show that the optimum temperature for the coarsening is 345k,and the best time is 20min; sensitization temperature has little effect on the coating and sensitization of the best time is 5min, activation of the best time is 5min. Do electroless plating on PET with increasing temperature, the effect of coating improve gradually. Coating effect decreases when the temperature reached 70 degrees. Do copper plating on PVC with increasing temperature, coating effect is gradually increased and effect of the coating decreases when the temperature reached 65 DEG C; PET copper the best pH of electroless plating on PVC is 12 and the best pH of PVC is 11. In the subsequent electroless copper plating reaction, we found that concentration of main salt and reducing agent on the coating has great influence on the experiment, the optimum concentration of copper sulfate is 20g / L, the optimu